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Is Part Of	http://hub.abes.fr/acs/periodical/orgnd7/1995/volume_14
has manifestation of work	http://hub.abes.fr/acs/periodical/orgnd7/1995/volume_14/issue_6/m/print http://hub.abes.fr/acs/periodical/orgnd7/1995/volume_14/issue_6/m/web
issue	6
is Is Part Of of	Reactions of 2-Butyne with Group 6-Group 10 Heterobimetallics. New Mixed-Metal Metallacycle Chemistry Masthead Ligand-Induced C,C Coupling and C,C Bond Breaking in Diarylfulvene Complexes of Cobalt(0) Organoaluminum and -gallium Thiolates. 1. Synthetic and X-ray Structural Studies Early Metal Carborane Chemistry. Generation and Reactivity of (C5Me5)(.eta.5-C2B9H11)TiMe Stereoselective Pauson-Khand Reactions via the Chiral [(alkyne)Co2(CO)5{P(OMe)3}] Aromatic Silylation of (Trimethylgermyl)benzene by Gaseous Me3Si+ Ions via Me3Ge+ Displacement Reaction of Aminocarbene Complexes of Chromium with Alkynes. 5. Influence of the Ring Size on the Product Distribution. Formation of Pyrroles from Pyrrolidine and Its Derivative-Substituted Carbene Complexes Alkyne Insertions into Metal-Metal Bonds. Synthesis of Heteronuclear Dimetalated Olefins by Insertion of MeO2CC.tplbond.CCO2Me into an Re-Fe Single Bond Synthesis and Characterization of a Phosphaalkyne-Bridged Pentairon Carbonyl Cluster. Crystal and Molecular Structure of [{Fe3Se2(CO)8}(.mu.-PCBut){Fe2Se(CO)6}] Synthesis of the First Redox-Active Organometallic Polymers Containing Cyclosiloxanes as Frameworks Reactions of H(PhMeSi)xH (x = 2, 3, 4) with Triflic Acid: Competitive Cleavage and Rearrangement Processes Vinylidene transition-metal complexes. 37. Novel Synthetic Route to Vinylidenerhodium(I) and -iridium(I) Complexes Using Vinyl Chlorides as Substrates Mono(pentamethylcyclopentadienyl)thorium Chemistry. Formation and Structural Characterization of a Novel Triflate-Bridged Dimeric Thorium Complex Pentadienyl-metal-phosphine chemistry. 30. Thiapentadienyl-iridium-phosphine chemistry Synthesis and Characterization of a Series of Mononuclear Tantalum(V) Hydride Compounds Containing Aryloxide Ligation Synthesis, Structure, and Fluxional Behavior of a Dihydrosilane Bearing an Aryldiamine Pincer Ligand Cationic Vinylidene-Bridged Complexes and Their Reactions with Alkynes to Yield Either Alkyne- and Vinylidene-Bridged or Bis(vinylidene) Products. Facile Interconversion between Terminal and Bridging Vinylidene Bonding Modes Synthesis and Reactivity of Silylboranes Carbonyl clusters as homogeneous catalysts. Kinetic and molecular aspects of the hydrogenation of diphenylacetylene promoted by an alkenyl-bridged triruthenium cluster complex. [Erratum to document cited in CA122:9301] Ruthenium-Mediated Hydrogenation of Carbon Dioxide by NaBH4 via the Formation of the Formate Complex C5Me5Ru(PCy3)(.eta.2-OCHO) Palladium-Assisted Formation of Carbon-Carbon Bonds. 3. Study of Reactions of Bis{.eta.2-(2,3,4-trimethoxy-6- acetylphenyl-C,O)}di(.mu.-chloro)dipalladium(II) with Symmetrical and Unsymmetrical Internal Alkynes. A Stoichiometric Route to Highly Functionalized Spirocyclic and Benzofulvene Compounds. Isolation of a .pi.-Allylic Palladium Intermediate. X-ray Structure of 10-(1-Hydroxyethyl)-6,7-dimethoxy-1,2,3,4-tetraphenylspiro[4.5]1,3,6,9-decatetraen-8-one Iridium(III)- and Rhodium(III)-Promoted Binuclear C-H Bond Activation of .pi.-Complexed Platinum(0) Ethylene and Phenylacetylene and Formation of Heterobimetallic Complexes. X-ray Crystal Structures of [(.eta.5-C5Me5)(PMe3)Ir(.mu.-H)(.mu.-.eta.2:.eta.1-CH2:CH)Pt(PPh3)2]2+[-OSO2CF3]2 and [(.eta.5-C5Me5)(PMe3)Rh(.mu.-H)(.mu.-.eta.2:.eta.1-PhC.sigma.bC)Pt(PPh3)2]2+[-OSO2CF3]2 Steric Effects in the Chemistry of Platinum Cluster Complexes Insertion of Isocyanides into Tantalum-Carbon Bonds of Azatantalacyclopropane Complexes. Crystal Structures of TaCpCl3(.eta.2-NRCMe2CNHR), TaCpMe(NR)(NRCMe:CMe2), and TaCp*Me(NR)(.eta.2-NR:CCMe2CMe:NR) (R = 2,6-Me2C6H3) Aminolysis of Dicationic Ruthenium Thiophene Complexes Photochemical Metal-to-Oxo Migrations of Aryl and Alkyl Ligands .mu.-Hydride Geometry and Dynamics in the Protic Acid Adducts of Triosmium Imidoyl Clusters Potential Energy Surface of the Reaction of the Silaformyl Anion and CO2 ((Trityloxy)methyl)boronic Esters H2- versus HSiMe3-Elimination in the Reactivity of HP(SiMe3)2 with Me2AlH to Yield a Mixed Organoaluminum Phosphide Trimer (.eta.6-Polyarene)Mn(CO)3+ Complexes as Manganese Tricarbonyl Transfer Reagents. A Convenient and General Synthetic Route to (arene)Mn(CO)3+ Complexes Chemistry of Organosilicon Compounds. 314. Preparation of (Pentamethyldisilanyl)lithium and Two Isomers of (Heptamethyltrisilanyl)lithium. Structural Characterization of (CH3)5Si2Li Stability in Solution of (Chloromethyl)palladium(II) Complexes: X-ray Structures of trans-Bis(triphenylphosphine)chloro(chloromethyl)palladium(II) and -platinum(II) and Comparison of the Relative Stabilities of Analogous Palladium and Platinum Chloromethyl Complexes Containing Phosphine Ligands Use of Tetradentate (N2O2) Ligands To Form Monomeric, Trimetallic Gallium Complexes Heterobimetallic .sigma.,.pi.-Acetylide-Bridged Complexes from Disubstituted 1,3-Butadiynes Synthesis, Structure, and Olefin Polymerization Activity of Vanadium(V) Catalysts Stabilized by Imido and Hydrotris(pyrazolyl)borato Ligands Reactivity of Bimetallic Compounds Containing Planar Tetracoordinate Carbon toward Unsaturated Organic Substrates Gas-Phase Chemistry of the Silaformamide Ion Aqueous Organometallic Chemistry: Structure and Dynamics in the Formation of (.eta.5-Pentamethylcyclopentadienyl)rhodium Aqua Complexes as a Function of pH Structural Characterization of Intermediates in the Rhodium-Catalyzed Reductive Carbonylation of Methanol: Rh(COMe)(I)2(dppp) and [Rh(H)(I)(.mu.-I)(dppp)]2 Regioselectivities of the Insertion of Dienes into Pd-R Bonds. Diastereoselection in the Isomerization of an (.eta.1-.eta.2-Enyl)palladium Complex to an (.eta.3-Allyl)palladium Complex Organotransition-Metal Metallacarboranes. 38. C2B3 and C2B4 Carborane Ligands as Cyclopentadienyl Analogs: Early Transition Metal Complexes Synthesis and Characterization of (.beta.-Diketonate)(7-tert-butoxynorbornadiene)copper(I) Compounds, a Series of New Copper CVD Precursors Comparison of the Properties of Polymethyl-1,1'-diheteroferrocenes of the Group 15 Elements Synthesis and Photochemistry of the Supramolecular (CpA)2Mo2(CO)6 Complex (CpA = .eta.5-C5H4CH2CH2NHC(O)-C14H7O2; C14H7O2 = 2-Anthraquinonyl). Reactivity of 19-Electron Complexes Covalently Bound to an Electron Acceptor Boron Trihalide Mediated Cleavage of Diethyl Ether with [Tris(trimethylsilyl)methyl]lithium Rate Constants and Arrhenius Parameters for the Reaction of Acyl Radicals with Bu3SnH and (Me3Si)3SiH The Aldol Reaction for 2,3-.eta.2-Furan Complexes of Osmium(II): Cyclization across C(2) and C(4) To Form a New Heterocycle Observation of a Slow Dissociative Process in Palladium(II) Complexes Molecular Structure of Monomeric (Pentamethylcyclopentadienyl)aluminum(I) by Gas-Phase Electron Diffraction Reductions of Cyclopentadienyltitanium Diolate and Dithiolate Species with Boron and Tin Hydrides Reactions of the Schiff Bases HN:CPh2 and PhN:CHPh with Titanocene- and Zirconocene-Generating Complexes Living Polymerization of Ethylene Catalyzed by Diene Complexes of Niobium and Tantalum, M(.eta.5-C5Me5)(.eta.4-diene)X2 and M(.eta.5-C5Me5)(.eta.4-diene)2 (M = Nb and Ta), in the Presence of Methylaluminoxane Imido/Oxo Exchange between Osmium and Tantalum as a Route to Os(NAr)2R2 and OsO(NAr)R2 Complexes (NAr = N-2,6-i-Pr2C6H3; R = CH2CMe3, CH2CMe2Ph, CH2SiMe3) and Attempts To Induce .alpha.-Hydrogen Abstraction To Give Alkylidene Complexes Synthesis and Photophysics of Luminescent Rhenium(I) Acetylides-Precursors for Organometallic Rigid-Rod Materials. X-ray Crystal Structures of [Re(tBu2bpy)(CO)3(tBuC.tplbond.C)] and [Re(tBu2bpy)(CO)3Cl] Reduction of Phenylchlorosilanes with Lithium 1-(Dimethylamino)naphthalenide: A New Access to Functionalized Silyllithiums .mu.2-.eta.2:.eta.1-Benzylidene(diphenylphosphino)maleic Anhydride Mediated PMe3 Addition to the Tricobalt Cluster Co3(CO)6[.mu.2-.eta.2:.eta.1-C(Ph)C:C(PPh2)C(O)OC(O)](.mu.2-PPh2). Structure and Redox Properties of the Arachno Cluster Co3(CO)4(PMe3)2[.mu.2-.eta.2:.eta.1-C(Ph)C:C(PPh2)C(O)OC(O)](.mu.2-PPh2) Unusual Rate Enhancement in the RhCl(PPh3)3-Catalyzed Hydrosilylation by Organosilanes Having Two Si-H Groups at Appropriate Distances: Mechanistic Aspects Synthesis and Reactivity of Platinum Complexes of Cyclic Alkynes and Tropynes Synthesis, Structure, and Reactivity of the Anionic Trinuclear Methanide NBu4[{Au(C6F5)3(PPh2CHPPh2)}2Au] Steric and "Indenyl" Effects in the Chemistry of Alkylidyne Complexes of Tungsten and Molybdenum New Diphosphine Ligands Based on Heterocyclic Aromatics Inducing Very High Regioselectivity in Rhodium-Catalyzed Hydroformylation: Effect of the Bite Angle Generation of Dinuclear Tartrate-Bridged Dicationic Titanocene Complexes 1,2-H Shift on Tetranuclear Ethynyl Complexes (.mu.4-C2H)(.eta.5-C5R5)FeMCo2(CO)n (M = Fe, Ru; n = 10, 11; R = H, Me) Unusual Hexacoordination in a Triorganotin Fluoride Supported by Intermolecular Hydrogen Bonds. Crystal and Molecular Structures of 1-Aza-5-stanna-5-halotricyclo[3.3.3.01.5]undecanes N(CH2CH2CH2)3SnF.cntdot.H2O and N(CH2CH2CH2)3SnX (X = Cl, Br, I) Structural Characterization and Simple Synthesis of {Pd[P(o-Tol)3]2}. Spectroscopic Study and Structural Characterization of the Dimeric Palladium(II) Complexes Obtained by Oxidative Addition of Aryl Bromides and Their Reactivity with Amines

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