| Abstract
| - New dendrimers3-[G‘1]−3-[G‘4] possessingfrom 6 to 48 N(CH2PPh2)2terminal groupsare described. The corresponding Pd, Pt, and Rh complexes[N(CH2PPh2)2MRR‘]y(y from 6to 24; generations 1−3) [M = Pd: R = R‘ = Cl, Br; R = Cl,R‘ = Me; R = Br, R‘ = Me; R =Cl, R‘ = COMe; R = Cl, R‘ = norbornyl-COMe. M = Pt: R= R‘ = Br, Cl, Me; R = Br, R‘ =Me. M = Rh: R, R‘ = acac] are prepared by reacting3-[G‘1]−3-[G‘3] with theappropriatetransition metal complexes.
- New dendrimers3-[G‘1]−3-[G‘4] possessingfrom 6 to 48 N(CH2PPh2)2terminal groups are described. The corresponding Pd, Pt, and Rhcomplexes[N(CH2PPh2)2MRR‘]y(y from 6 to 24; generations 1−3) [M = Pd: R = R‘= Cl, Br; R = Cl, R‘ = Me; R = Br, R‘ = Me; R = Cl, R‘ =COMe; R = Cl, R‘ = norbornyl COMe. M = Pt: R = R‘ =Br, Cl, Me; R = Br, R‘ = Me. M = Rh: R, R‘ = acac] areprepared by reacting3-[G‘1]−3-[G‘3] with theappropriate transition metalcomplexes.
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