| Abstract
| - The novel air- and moisture-stable dihydrido(methyl)platinum(IV) complex TpPtH2Me (1; Tp = hydridotris(pyrazolyl)borate) is formed as the sole product by the reaction of TpPtMeCO (2) with water. Complex 1 was characterized by elemental analysis, 1H NMR, 13C NMR, and FTIR. The proposed mechanism of the reaction involves an initial nucleophilic attack by a water molecule on the coordinated carbonyl in 2 with subsequent release of CO2 followed by protonation at the platinum center to produce 1.
- The novel air- and moisture-stable dihydrido(methyl)platinum(IV) complex TpPtH2Me (1; Tp = hydridotris(pyrazolyl)borate) is formed as the sole productby the reaction of TpPtMeCO (2) with water. Complex 1was characterized by elemental analysis, 1H NMR, 13CNMR, and FTIR. The proposed mechanism of thereaction involves an initial nucleophilic attack by a watermolecule on the coordinated carbonyl in 2 with subsequent release of CO2 followed by protonation at theplatinum center to produce 1.
|
