| Abstract
| - Preparation of the terminal nitrido anion -[NNb(N[iPr]Ar)3] and the niobazene trimer {(μ-N)Nb(N[iPr]Ar)2}3 (iPr = CH(CH3)2 or CH(CD3)2, Ar = 3,5-C6H3Me2) entails cooperative splitting of dinitrogen upon reduction of heterobimetallic paramagnetic dinitrogen complex (Ar[R]N)3Mo(μ-N2)Nb(N[iPr]Ar)3 (R = tBu or C(CD3)2 CH3).
- Preparation of the terminal nitrido anion-[NNb(N[iPr]Ar)3] and the niobazene trimer {(μ-N)Nb(N[iPr]Ar)2}3 (iPr = CH(CH3)2 or CH(CD3)2, Ar = 3,5-C6H3Me2) entails cooperative splitting of dinitrogen uponreduction of the heterobimetallic paramagnetic dinitrogen complex (Ar[R]N)3Mo(μ-N2)Nb(N[iPr]Ar)3 (R = tBuor C(CD3)2 CH3).
|
