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η1-Ligation versus Pnictogen−Carbon Double BondCleavage: The Contrasting Behavior of Phospha- andArsaalkenes [Tp*(CO)2M⋮C−EC(NMe2)2] [E = P, As; M= Mo, W; Tp* = HB(3,5-Me2pz)3] toward [Au(CO)Cl]
Synthesis and Photophysical Properties of DinuclearOrganometallic Rhenium(I) Diimine Complexes Linkedby Pyridine-Containing Macrocyclic PhenylacetyleneLigands
A Stable Copper(I)−Triazacyclononane Complex with anIntramolecularly Coordinated Alkyne Group
Iron(II) and Ruthenium(II) Complexes ContainingBidentate, Tied-Back Diphosphonite Ligands. X-rayStructure ofcis-FeMe2[(−OCH2CEt2CH2O−)PCH2CH2P(−OCH2CEt2CH2O−)]2
Osmium−Antimony Higher Nuclearity Clusters
Origin of the Enantioselectivity in the HydrogenTransfer Reduction of Carbonyls by a Rhodium(I)Complex: A Theoretical Study
New C2v- and Chiral C2-Symmetric Olefin PolymerizationCatalysts Based on Nickel(II) and Palladium(II) DiimineComplexes Bearing 2,6-Diphenyl Aniline Moieties: Synthesis, Structural Characterization, and First Insightinto Polymerization Properties
Synthesis and X-ray Crystal Structures ofPnictogen-Bridged, Bimetallic Complexes ContainingMain Group Metal and Tricarbonylnickel Fragments
Conformational Properties of Substituted Ferrocenes: Experimental and Theoretical Studies of the MolecularStructures of 1,1‘-Di-tert-butylferrocene andIsopropylferrocene
Synthesis of Silatranes with All Six-Membered Rings.Influence of Steric Effect on Structure and NMRBehavior1a,b
Synthesis, Structure, and Application of[PhNMe2H][B{C6F4C(C6F5)2F}4]
Tetramethylcyclopentadienyl vs CyclopentadienylSubstituents. Synthesis and Structural Characterizationof Organolanthanide Compounds Derived from theVersatile Ligand Me2Si(C5Me4H)(C2B10H11)
Synthesis and Reactivity of(Tricarbonyl)(1-ethoxycarbonyl-2-methylpentadienyl)iron(1+)Cation
Matrix Photochemistry of Methyltrioxorhenium(VII),CH3ReO3: Formation of the Methylidene TautomerH2CRe(O)2OH and Its Potential Relevance to OlefinMetathesis
Origin of Enantioreversal in the Rhodium-CatalyzedAsymmetric Hydrogenation of Prochiral Enamides andthe Effect of the α-Substituent
Homotrimetallic Oxazolo-Ferrocene ComplexesDisplaying Tunable Cooperative Interactions betweenMetal Centers and Redox-Switchable Character
Kinetics of Substitution of Weakly Coordinating Nitrateby Chloride in (η5-Cp)Ru(CO)(ER3)ONO2 (ER3 = AsPh3,PPh3, P(p-anisyl)3, PPh2(o-anisyl), P(OPh)3) inDichloromethane
Syndiotactic CO/Styrene Copolymerization Catalyzed byα-Diimine Pd(II) Complexes: Regio- and StereochemicalControl
Ru-σ-butadiynyl Complexes of theTetraanilinopyridinatodiruthenium Core: Formation ofa Bis-adduct
Menthyl-Functionalized Chiral Nonracemic MonoindenylComplexes of Rhodium, Iridium, Cobalt, andMolybdenum
Alkylidyne Complexes of Molybdenum and TungstenThat Contain the [(3,4,5-C6H2F3NCH2CH2)2NMe]2- Ligand
BINOL Compounds of Group 13
Theoretical Studies of Inorganic and OrganometallicReaction Mechanisms. 18. Catalytic TransferDehydrogenation of Alkanes by an Iridium(III) PincerComplex
Hydrogen/Deuterium Exchange Kinetics by aSilica-Supported Zirconium Hydride Catalyst: Evidencefor a σ-Bond Metathesis Mechanism
Interactions of Cationic and Neutral MolybdenumComplexes with β-Cyclodextrin Host Molecules
Self-Assembly Molecular Architectures IncorporatingFluorene- and Carbazole-Based BichromicOligopyridines. Novel Photoactive Materials
Selective Ion Pairing in [Ir(bipy)H2(PRPh2)2]A (A = PF6,BF4, CF3SO3, BPh4, R = Me, Ph): ExperimentalIdentification and Theoretical Understanding
Sterically Controlled Silacycloalkyl Diamide Complexesof Titanium(IV): Synthesis, Structure, and CatalyticBehavior of (cycl)Si(NBut)2TiCl2 [(cycl)Si =Silacyclobutane, Silacyclopentane, Silacyclopentene, andSilacyclohexane]
Remarkable Reactions of Cationic Carbyne Complexes ofManganese and Rhenium with Diiron Anions[Fe2(μ-CO)(μ-SeR)(CO)6]-. A Route to RSe-BridgedDimetal Bridging Carbene Complexes
Photochemical Reactivity of Group 9 Metal PinacolateComplexes
Remarkable Reactions of (η4-1-azadiene)Fe(CO)3Complexes with Aryllithium Reagents. Syntheses andStructures of Novel Chelated Furanyl-CoordinatedAlkoxy(amino)carbeneiron, η4-Azadiene-Coordinated 17eAcyliron, and Iron Inner Salt Complexes
Investigation of the Redox Properties of aCp*Co(dithiolene) Complex. Evidence of the Formationof a Dimeric Dicationic Species: [Cp*Co(dddt)]22+
Hydrido−Rhodium(I) and −Iridium(I) ComplexPromoted Ring-Opening Isomerization ofUnsymmetrically Substituted Methylenecyclopropanesinto 1,3-Dienes. Structures of Intermediates andReaction Pathways
Donor-Ligand-SubstitutedCyclopentadienylchromium(III) Complexes: A New Classof Alkene Polymerization Catalyst. 2.Phosphinoalkyl-Substituted Systems
Ferrocenediyl-Bridged Triiron Complexes
Organic Syntheses via Transition-Metal Complexes. 110.A Convenient Regio- and Stereoselective Approach tothe Angular Allylation of Bicyclic CyclopentadienesGenerated by the (1-Alkynyl)carbene Complex Route
Cationic Vinyl and Dicationic Carbene Ruthenium(II)Complexes from a Vinylidene(hydrido) Precursor
Metal-Catalyzed Hydroboration and Diboration ofThiocarbonyls and Vinyl Sulfides
Δ2- and Δ3-Azaosmetine Complexes as Intermediates inthe Stoichiometric Imination of Phenylacetylene withOximes
Generation of the 15-Electron Rhodium(II) Complex[RhCl(PPh3)3]+ by 1-Electron Oxidation of Wilkinson'sCatalyst
Metal Template Effects on the Asymmetric CycloadditionReaction between Diphenylvinylphosphine and2-Diphenylphosphinofuran
Phosphinimide−Phosphinimide Ligands: New BulkyLigands for Ethylene Polymerization Catalysts
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