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À propos de : Facilitated dπ−pπ* Transition in a Novel Organoboronπ-Conjugated Polymer Including aRuthenium−Phosphine Complex        

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  • Facilitated dπ−pπ* Transition in a Novel Organoboronπ-Conjugated Polymer Including aRuthenium−Phosphine Complex
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  • A facilitated dπ−pπ* transition was observedin a boron−ruthenium conjugated system prepared byhydroboration polymerization between mesitylboraneand a ruthenium−phosphine complex containing tetrayne. In the UV−vis absorption spectrum of the obtained polymer, the absorption maximum of the MLCTband (dπ−pπ* transition) was highly bathochromicallyshifted by 141 nm relative to that of the tetraynemonomer.
  • A facilitated dπ−pπ* transition was observed in a boron−ruthenium conjugated system prepared by hydroboration polymerization between mesitylborane and a ruthenium−phosphine complex containing tetrayne. In the UV−vis absorption spectrum of the obtained polymer, the absorption maximum of the MLCT band (dπ−pπ* transition) was highly bathochromically shifted by 141 nm relative to that of the tetrayne monomer.
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