| Abstract
| - Important intermediates in regiospecific hydride reduction of NAD(P) model compounds were detected by various spectroscopic methods. The metal hydrido complexes 1 and 2 react with the NAD(P) models to give 1:1 adducts (3), which are cleaved to the 1,4-dihydro form of the models and the solvento complexes, quantitatively.
- Important intermediates in regioslective hydride reduction of NAD(P) model compounds weredetected by various spectroscopic methods. The metalhydrido complexes [Ru(tpy)(bpy)H]+ and [Re(bpy)(CO)3H] react with the NAD(P) models to give 1:1adducts, which are cleaved to the 1,4-dihydro form ofthe models and the solvento complexes, quantitatively.
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