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À propos de : Probing the Niobium Metallaaziridine Functionality        

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  • Probing the Niobium Metallaaziridine Functionality
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Abstract
  • Borane abstraction from 4-BH4 was used toaccess the metallaaziridine-hydride functionality in aniobium system. Unlike its known molybdenum analog,proposed intermediate 4-H displays reactivity characteristic of electrophilic early transition-metal hydridecomplexes.
  • Depicted is the retrosynthetic strategy that inspired the synthesis of metallaaziridine borohydride 4-BH4, the preparation, molecular structure, and reactivity of which are detailed in this contribution.
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