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À propos de : Samarium-Mediated Tandem Reactions of o-Carborane.Synthesis and Molecular Structure of[{η5:η1:η6-Me2Si(C9H5CH2CH2G)(C2B10H10)Sm}2(μ-Cl)][Li(THF)4](G = NMe2 and OMe)        

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  • Samarium-Mediated Tandem Reactions of o-Carborane.Synthesis and Molecular Structure of[{η5:η1:η6-Me2Si(C9H5CH2CH2G)(C2B10H10)Sm}2(μ-Cl)][Li(THF)4](G = NMe2 and OMe)
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  • New metallacarboranes bearing a (nido-RC2B10H10)24- ligand, [{η5:η1:η6-Me2Si(C9H5CH2CH2G)(C2B10H10)Sm}2(μ-Cl)][Li(THF)4] (G = NMe2 (1), OMe(2)), have been prepared and structurally characterizedby treatment of SmI2(THF)x with 1 equiv of [Me2Si(C9H5CH2CH2G)(C2B10H10)]Li2(OEt2)2·LiCl in THF via unexpected samarium-mediated tandem reactions.
  • New metallacarboranes bearing a (nido-RC2B10H10)24- ligand, [{η5:η1:η6-Me2Si(C9H5CH2CH2G)(C2B10H10)Sm}2(μ-Cl)][Li(THF)4] (G = NMe2 and OMe), have been prepared and structurally characterized via unexpected samarium-mediated tandem reactions.
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