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À propos de : Unprecedented Formation of Dinuclear Platinum(II)Complexes with μ-Alkenylidene Bridging Ligands fromReactions of Pt(dppm)2Cl2 with Alkyl Acetylenes        

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  • Unprecedented Formation of Dinuclear Platinum(II)Complexes with μ-Alkenylidene Bridging Ligands fromReactions of Pt(dppm)2Cl2 with Alkyl Acetylenes
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  • A new series of dinuclear platinum(II) complexes, [Pt2(μ-dppm)(dppm-P,P‘)(μ-CCRPPh2CH2PPh2-P)(C⋮CR)]2+ (R = alkyl), has been synthesized, and thestructure of one of the complexes was confirmed by X-raycrystallography. A proposed mechanism to account fortheir formation from the corresponding alkynyl precursors is suggested. Their luminescence properties are alsoreported.
  • A new series of dinuclear platinum(II) complexes, [Pt2(μ-dppm)(dppm-P,P‘)(μ-CCRPPh2CH2PPh2-P)(C⋮CR)]2+ (R = alkyl), has been synthesized, and the structure of one of the complexes was confirmed by X-ray crystallography. A proposed mechanism to account for their formation from the corresponding alkynyl precursors is suggested. The luminescence and electrochemical properties are also reported.
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