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| - Aqueous Organometallic Chemistry with NitrogenLigands: Synthesis of Hydrophilic Platinum(0) OlefinComplexes
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| - Reactions of hydrophilic unsymmetrical pyridine−imine chelating ligands with Pt(η2-norbornene)3in the presence of olefins that contain electron-withdrawing substituents afford water-soluble three-coordinate Pt(0) complexes. The stability of these organometalliccomplexes in aqueous solution is dependent on theposition of the hydrophilic charged substituents in thechelating ligand and the electronic nature of the coordinated olefin.
- Reactions of hydrophilic unsymmetrical pyridine−imine ligands with Pt(η2-norbornene)3 in the presence of olefins that contain electron-withdrawing substituents afford water-soluble three-coordinate Pt(0) complexes. The stability of these organometallic complexes in aqueous solution is dependent on the position of the hydrophilic charged substituents in the chelating ligand and the electronic nature of the coordinated olefin.
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