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À propos de : In Situ Formation of Mixed Phosphine−ImidazolylidenePalladium Complexes in Room-Temperature IonicLiquids        

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  • In Situ Formation of Mixed Phosphine−ImidazolylidenePalladium Complexes in Room-Temperature IonicLiquids
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  • The in situ formation of a mixed phosphine−imidazolylidene palladium complex, 3, in the room-temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]) has been observed under conditions employed in many palladium-catalyzed coupling reactions. This paper highlights the noninnocent nature of imidazolium-based ionic liquids and the implications of this for ionic liquid mediated palladium catalysis.
  • The in situ formation of a mixed phosphine−imidazolylidene palladium complex, 3, in the room-temperature ionic liquid 1-butyl-3-methylimidazoliumtetrafluoroborate ([bmim][BF4]) has been observed underconditions employed in many palladium-catalyzed coupling reactions. This paper highlights the noninnocentnature of imidazolium-based ionic liquids and theimplications of this for ionic liquid mediated palladiumcatalysis.
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