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À propos de : Crystal Structure of the Organometallic Polymer[Pd{CH2C(O)Me}Cl]n, Determined by X-ray PowderDiffraction Methods        

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  • Crystal Structure of the Organometallic Polymer[Pd{CH2C(O)Me}Cl]n, Determined by X-ray PowderDiffraction Methods
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  • The crystal and molecular structure of therecently synthesized organometallic [Pd{CH2C(O)Me}Cl]n polymer (Organometallics 2001, 20, 2767) has beenunravelled by ab initio powder diffraction methods andshown to possess a different stereochemistry from themodel proposed on the basis of IR spectral data.
  • X-ray powder diffraction methods have been employed to unravel the structure of the recently synthesized organometallic [Pd{CH2C(O)Me}Cl]n polymer (Organometallics2001, 20, 2767) and showed the μ2-bridging nature of the chlorides and of the acetonyl fragments, thus dismissing the structural model originally proposed on the basis of IR spectral data.
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