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À propos de : Ferrocenoyl-Substituted Cinchona Alkaloids: Synthesis,Structure, and Application in Asymmetric CatalyticOxidation        

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  • Ferrocenoyl-Substituted Cinchona Alkaloids: Synthesis,Structure, and Application in Asymmetric CatalyticOxidation
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  • Ferrocenoyl-substituted Cinchona alkaloidswere synthesized from ferrocenecarboxylic acid and thefree Cinchona alkaloids and represent readily availableorganometallic auxiliaries. They were employed as a rareexample of chiral ferrocenyl ligands in asymmetricoxidation chemistry.
  • Ferrocenoyl-substituted Cinchona alkaloids have been synthesized in a one-step procedure. These compounds act as ligands in Sharpless dihydroxylation and aminohydroxylation of olefins and represent a rare example of ferrocene-based ligands for oxidation catalysis.
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