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À propos de : Synthesis of a Dirhodium(I) Bisimidazolium CarbeneComplex and Catalytic Activity towardHydroformylation of Olefins. High-Pressure NMRSpectroscopy of the Catalyst under Catalytic Conditions        

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  • Synthesis of a Dirhodium(I) Bisimidazolium CarbeneComplex and Catalytic Activity towardHydroformylation of Olefins. High-Pressure NMRSpectroscopy of the Catalyst under Catalytic Conditions
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  • A new dirhodium(I) bisimidazolium-carbene complex has been obtained and fullycharacterized by means of NMR spectroscopy and single-crystal X-ray diffraction. Thecomplex has been used as catalyst in hydroformylation reactions, showing selectivity on thebranched aldehyde. High-pressure NMR spectroscopy provides evidence that the dinuclearunit is maintained under catalytic conditions.
  • A new dirhodium(I) bisimidazolium-carbene complex has been obtained and fully characterized by means of NMR spectroscopy and single-crystal X-ray diffraction. The complex has been used as catalyst in hydroformylation reactions, showing high selectivity on the branched aldehyde. High-pressure NMR spectroscopy provides evidence that the dinuclear unit is maintained under catalytic conditions.
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