| Abstract
| - The solid-state structure and NMR parameters of the monomeric heavier carbene analogue [Pb{Ph2PC(H)Py}{N(SiMe3)2}] (1), obtained via deprotonation of the phosphane Ph2P(CH2Py) with [Pb{N(SiMe3)2}2], are discussed. The [Ph2PC(H)Py]- anion in 1 should be regarded as an amide rather than a carbanion or phosphanide.
- The solid-state structure and NMR parameters of the heavier carbene analogue [Pb{Ph2PC(H)Py}{N(SiMe3)2}] (1), obtained in the reaction of the phosphane Ph2P(CH2Py) with [Pb{N(SiMe3)2}2], are discussed.
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