| Abstract
| - The first (CH)10-bridged bimetallic complexes, [RuCl(CO)(PPh3)2]2(μ-CHCHCHCHCHCHCHCHCHCH) and [RuCl(CO)(PMe3)3]2(μ-CHCHCHCHCHCHCHCHCHCH), have been synthesized and characterized.
- Treatment of RuHCl(CO)(PPh3)3 with(3E,5E,7E)-HC⋮CCHCHCHCHCHCHC⋮CHproduces [RuCl(CO)(PPh3)2]2(μ-CHCHCHCHCHCHCHCHCHCH). The latter complex reacts withPMe3 to give [RuCl(CO)(PMe3)3]2(μ-CHCHCHCHCHCHCHCHCHCH), the structure of which has beenconfirmed by X-ray diffraction. The electrochemicalproperties of the latter C10H10-bridged complex have beeninvestigated.
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