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À propos de : Vanadocene-Mediated Ionization of Water in the Aqua Species[H2O·B(C6F5)3]: Structural Characterization of the Hydride andHydroxide Complexes [Cp2V(μ-H)B(C6F5)3] and[Cp2V(μ-OH)B(C6F5)3]        

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  • Vanadocene-Mediated Ionization of Water in the Aqua Species[H2O·B(C6F5)3]: Structural Characterization of the Hydride andHydroxide Complexes [Cp2V(μ-H)B(C6F5)3] and[Cp2V(μ-OH)B(C6F5)3]
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  • The reaction of Cp2V with B(C6F5)3 in the presence of water leads to the hydride complex [Cp2V(μ-H)B(C6F5)3] (1) and the hydroxide complex [Cp2V(μ-OH)B(C6F5)3] (2), both of which have been characterized by X-ray structure determinations. Both complexes are derived from the ionization of H2O in the presence of B(C6F5)3.
  • The reaction of Cp2V with B(C6F5)3 in the presenceof water leads to the hydride complex [Cp2V(μ-H)B(C6F5)3] (1)and the hydroxide complex [Cp2V(μ-OH)B(C6F5)3] (2), both ofwhich have been characterized by X-ray structure determinations. Both complexes are derived from the ionization of waterin the presence of B(C6F5)3.
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