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À propos de : New Structural Forms of Organostannoxane Macrocycle Networks        

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  • New Structural Forms of Organostannoxane Macrocycle Networks
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  • The reaction of pyrazole-3,5-dicarboxylic acid with dibenzyltin dichloride in the presence of potassium hydroxide affords a novel 2D network containing rectangular box type hexatin units interconnected by two Bz2SnCl bridging groups. Hydrolysis of the latter affords a polymeric tape containing alternate hexatin macrocycle and tetratin ladder motifs.
  • The reaction of pyrazole-3,5-dicarboxylic acid withdibenzyltin dichloride in the presence of potassium hydroxideaffords a novel 2D network containing rectangular box typehexatin units interconnected by two Bz2SnCl bridging groups.Hydrolysis of the latter affords a polymeric tape containingalternate hexatin macrocycle and tetratin ladder motifs.
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