| Abstract
| - The reaction of a phosphole-2,5-diol with a tripyrromethane in the presence of BF3 generates, after oxidation byDDQ, a P-confused carbaporphyrinoid whose X-ray crystalstructure analysis has been performed. The steric bulk of thephosphorus subunit prevents the formation of the expectedphosphaporphyrin.
- The reaction of a phosphole-2,5-diol with a tripyrromethane in the presence of BF3 generates, after oxidation by DDQ, a P-confused carbaporphyrinoid whose X-ray crystal structure analysis has been performed. The steric bulk of the phosphorus subunit prevents the formation of the expected phosphaporphyrin.
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