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À propos de : Do Lead Analogues of Alkynes Take a Multiply Bonded Structure?        

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  • Do Lead Analogues of Alkynes Take a Multiply Bonded Structure?
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  • It is found from theoretical calculations thatAr*PbPbAr* (Ar* = C6H3-2,6-(C6H2-2,4,6-iPr3)2) has a multiply bonded structure in solution, although a singly bondedstructure with a highly trans-bent core skeleton has beenreported from the X-ray crystal study.
  • Theoretical calculations show that Ar*PbPbAr* (Ar* = C6H3-2,6-(C6H2-2,4,6-iPr3)2) takes a multiply bonded structure (M) in solution, although it has a singly bonded structure (S) with a highly trans-bent core skeleton in the crystal state.
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