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Group 4 Metal Atom Reactions with CF3Cl, CFCl3, CF3Br, andCF3I: A Matrix Infrared Spectroscopic and DFT Investigation ofCompetitive α-Halogen Transfer to Form Triplet XC÷MX3Complexes
Immobilized Chiral ortho-Metalated Dirhodium(II) Compounds asCatalysts in the Asymmetric Cyclopropanation of Styrene withEthyl Diazoacetate
Reactions of SiH-Functionalized Cyclopentadienes with MetalCarbonyls
Stereoselective Cyclometalation of Planar Pro-chiral(η6-Arene)tricarbonylchromium Complexes withOC-6-[Ru(CO)2Cl2]n
Nickel Olefin Complexes Supported by GaI(DDP)
Stabilization of a Transient Diorganogermylene by anN-Heterocyclic Carbene
Ab Initio Calculations of Thermodynamic Hydricities ofTransition-Metal Hydrides in Acetonitrile
A Combined Theoretical−Experimental Study of the Inclusion ofNiobocene Dichloride in Native and Permethylated β-Cyclodextrins
PalladiumII Complexes of the (N,C,N)SnCl Stannylene
Reactivity of Silica-Supported Hafnium Tris-neopentyl withDihydrogen: Formation and Characterization of Silica SurfaceHafnium Hydrides and Alkyl Hydride
Highly Stereoselective One-Pot Procedure to Prepare UnsymmetricalBis- and Tris-chalcogenide Alkenes via Addition of Chalcogens toAlkynes
Heptahexaenylidene Complexes: Synthesis and Characterization ofthe First Complexes with an MCCCCCCCR2 Moiety(M = Cr, W)
Expanding Heteroscorpionates. Facile Synthesis of New HybridScorpionate/Cyclopentadienyl Ligands and Their Lithium andGroup 4 Metal Compounds: A Combined Experimental andDensity Functional Theory Study
Iron Trichloride Mediated Allylation of Lithium Alkoxides throughan Unusual Carbon−Oxygen Bond Cleavage
Peripheral Functionalization of Diruthenium Compounds via HeckReactions
Trifluoromethyl-Substituted Bis(pyrazolyl)methanes as Ligands forCopper and Silver: Synthesis and Spectroscopic and StructuralCharacterization
Trimethylsilylated Allyl Complexes of the Heavy Alkali Metals,M[1,3-(SiMe3)2C3H3](thf)n (M = K, Cs)
In-Silico Prediction of Pd-Catalyzed Cross-Coupling Processes: Dibenzylidene Acetone (dba) Ligand Control
Reaction of Cyclopentadienyl Ruthenium Complexes with aCarborane Anion: Effect of the Spectator Ligands on theSubstitution Site
Late Transition Metal Catalyzed Intramolecular Hydroamination: The Effect of Ligand and Substrate Structure
Ph(3-n)XnSnCH2-16-crown-5 (X = F, Cl, Br, I, SCN; n = 1, 2): Intramolecular O → Sn Coordination versus Ditopic Complexationof Sodium Thiocyanate
A Discrete Ortho-Lithiated Acetophenone Imine Derivative: Isolation, Characterization, and Synthesis of Group IV MetalComplexes
Synthesis of Bicyclo[4.1.0]heptenes via Palladium-CatalyzedIntramolecular Coupling−Cyclization of3-(Cyclohexa-2,4-dienyl)pentane-2,4-dione with β-Styryl Bromides
Hydrogen Transfer to Ketones Catalyzed by Shvo's RutheniumHydride Complex: A Mechanistic Insight
Reactions of (η5-C5Me5)Ir(PMe3)(SH)2 and(η5-C5Me5)Ir(PMe3)(SH)(H) with Thionylaniline (PhNSO) to GiveNovel Iridium S3O and S2O Complexes
Reactivity of CpCo 16e Half-Sandwich Complexes Containing aChelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolateLigand toward Phenylacetylene
Zn(tmp)2: A Versatile Base for the Selective Functionalization ofC−H Bonds
Catalytic Activity of Bis-phosphine Ruthenium(II)−AreneCompounds: Chemoselective Hydrogenation and MechanisticInsights
Photochemical cis−trans Isomerization ofcis-(η6-1,2-Diphenylethene)Cr(CO)3 and the Molecular Structure oftrans-(η6-1,2-Diphenylethene)Cr(CO)3
Influence of Ligand Geometry in Bimetallic Ytterbocene Complexesof Bridging Bis(bipyridyl) Ligands
Unprecedented Enantioselectivity in a Cluster-Based CatalyticSystem
New Pincer-Type Diphosphinito (POCOP) Complexes of Nickel
γ-Substituted Vinylidene, Chroman-2-ylidene, andHexahydrochromen-2-ylidene from Ruthenium Allenylidene/Alkenylcarbyne Complexes
Silica-Grafted Diethylzinc and a Silsesquioxane-Based Zinc AlkylComplex as Catalysts for the Alternating Oxirane−Carbon DioxideCopolymerization
Formation of HC⋮ReH3 in Methane Activation by Rhenium Atoms:Observation of the Elusive Methylidyne C−H Stretching Absorption
Rhodium Silyl Hydrides in Oxidation State +5: Classical orNonclassical?
Synthesis, Characterization, and Reactivity of Niobium andTantalum Complexes Bearing Metal−Nitrogen Bonds. X-rayMolecular Structure of [Nb(C5H4SiMe3){NH(CH2)2-η-NH2}Cl3] andthe Novel Tetranuclear Niobium Oxo Derivative[{Nb(C5H4SiMe3)Cl(μ2-O)}4(Cl)2(μ3-O)]
Formation of (C5Me5)2U(EPh)Me, (C5Me5)2U(EPh)2, and(C5Me5)2U(η2-TeC6H4) from (C5Me5)2UMe2 and PhEEPh(E = S, Se, Te)
Enantioselective Preparation of a Chiral-at-Metal Cp*Ir(NHC)Complex and Its Application in the Catalytic Diboration of Olefins
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