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À propos de : The First Imidazolium-Substituted Metal Alkylidene        

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  • The First Imidazolium-Substituted Metal Alkylidene
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  • A ruthenium complex coordinated by a bidentatearyloxy-NHC ligand has offered the first example of animidazolium-substituted metal alkylidene, an analogue of existing phosphonium alkylidenes and metal-substituted ketenes.Investigation of the molecular structure and the quantumchemically obtained electronic structure sheds light on thenature of this new compound and the bonds central to itsformation.
  • A ruthenium complex coordinated by a bidentate aryloxy-NHC ligand has offered the first example of an imidazolium-substituted metal alkylidene, an analogue of existing phosphonium alkylidenes and metal-substituted ketenes. Investigation of the molecular structure and the quantum chemically obtained electronic structure sheds light on the nature of this new compound and the bonds central to its formation.
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