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| Title
| - Aluminum Alkyl-Mediated Route to Novel N,N,O-Chelates forFive-Coordinate Iron(II) Chloride Complexes: Synthesis,Structures, and Ethylene Polymerization Studies
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| - Two five-coordinate iron(II) chloride complexesbearing 2-imine-6-(methyl alcohol)pyridine chelates have beenprepared via an aluminum-mediated methyl migration routefrom the corresponding 2-acetyl-6-iminopyridine. Both ironcomplexes display moderate activity for ethylene polymerizationon treatment with excess methylaluminoxane, affording highlylinear polymers along with some oligomeric products.
- Five-coordinate iron(II) chloride complexes bearing 2-imine-6-(methyl alcohol)pyridine chelates have been synthesized via an aluminum-mediated methyl migration route. Both iron complexes display moderate activity for ethylene polymerization on treatment with excess methylaluminoxane, affording highly linear polymers along with some oligomeric products.
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