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À propos de : Self-Assembled Bidentate Ligands for Ruthenium-CatalyzedHydration of Nitriles        

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  • Self-Assembled Bidentate Ligands for Ruthenium-CatalyzedHydration of Nitriles
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  • Ruthenium complexes bearing ligands self-assembled through complementary hydrogen bonding were synthesized and used as catalysts for the hydration of nitriles.
  • Novel bis(acetylacetonato)ruthenium(II) complexesbearing the 6-diphenylphosphino-N-pivaloyl-2-aminopyridineand 3-diphenylphosphinoisoquinolone ligands were synthesized.Molecular structures of these complexes were studied in solutionand also in the solid state, and unusual hydrogen-bondingpatterns were identified. The prepared compounds constituteactive catalysts for the hydration of nitriles to amides underneutral conditions.
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