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À propos de : Lanthanide Carbene Halides through Protonolysis of Ln−N Bonds by Imidazolium Salts: Synthesis and Structure of Salicylaldiminato-Functionalized N-Heterocyclic Carbene Lanthanide Bromides        

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  • Lanthanide Carbene Halides through Protonolysis of Ln−N Bonds by Imidazolium Salts: Synthesis and Structure of Salicylaldiminato-Functionalized N-Heterocyclic Carbene Lanthanide Bromides
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  • The three salicylaldiminato-functionalized N-heterocyclic carbene lanthanide bromides L2LnBr (Ln = Nd (2), Sm (3), Er (4); L = [3,5-tBu2-2-(O)C6H2CHNCH2CH2(C{NCHCHNiPr})]) with early to late lanthanide metals were conveniently synthesized in moderate yields by a protonolysis strategy via the direct reaction of LiLn(NiPr2)4 with [H2L]Br (1). All complexes were characterized by X-ray crystal determinations.
  • The three salicylaldiminato-functionalized N-heterocyclic carbene lanthanide bromides L2LnBr (Ln = Nd (2), Sm (3), Er (4); L = [3,5-tBu2-2-(O)C6H2CHNCH2CH2(C{NCHCHNiPr})]) with early to late lanthanide metals were conveniently synthesized in moderate yields by a protonolysis strategy via the direct reaction of LiLn(NiPr2)4 with [H2L]Br (1).
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