Regioselective Zirconophosphination of 1-Alkenes: A Versatile Route for the Synthesis of β-Functionalized Alkyldiphenylphosphine Oxides in the Presence of CuCl
Zirconocene−alkene complexes Cp2ZrPMe3(CH2CHR) reacted with chlorodiphenyllphosphine to form zircono-ethylphosphine derivatives with high regioselectivity, which could be easily transformed into various functionalized alkyldiarylphosphine oxides in the presence of CuCl.
Zirconocene−alkene complexes Cp2Zr(PMe3)(CH2CHR) reacted with chlorodiphenylphosphine to form zircono-ethylphosphine derivatives with high regioselectivity, which could be converted into various β-functionalized alkyldiphenylphosphine oxides in the presence of CuCl.