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À propos de : Reactivity of Dinuclear Rhodium(I) Macrocycles Formed via the Weak-Link Approach        

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  • Reactivity of Dinuclear Rhodium(I) Macrocycles Formed via the Weak-Link Approach
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  • The reaction of a macrocyclic Rh(I) complex having hemilabile PO ligands with Cl− results in Rh−O bond breakage and yields a Cl-bridged tetranuclear Rh(I) complex, which was characterized by a single-crystal X-ray diffraction study. Reactivity of the complex with CO and halide abstracting agents is described.
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