| Abstract
| - The first organometallic cadmium hydroxylamide [Cd(MeCd)4(ONEt2)6] (1) has been prepared by alkane elimination from dimethylcadmium upon treatment with N,N-diethylhydroxylamine and characterized by variable-temperature NMR spectroscopy (1H, 13C, 113Cd), single-crystal X-ray diffraction, and elemental analysis. In the solid state compound 1 comprises an Cd5N6O6 backbone with a central octahedral coordinate Cd atom, while all 12 donor atoms are attached to the 5 Cd nuclei whereas in solution it is of highly dynamic nature.
- The simple starting materials dimethylcadmium and N,N-diethylhydroxylamine lead to the selective formation of a pentanuclear aggregate [Cd(MeCd)4(ONEt2)6] with central six-coordinate and peripheral four-coordinate Cd atoms, which is a highly dynamic compound as shown by NMR including that of 113Cd.
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