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À propos de : Characterization of two new stable block copolymer mesophases by synchrotron small-angle scattering        

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  • Characterization of two new stable block copolymer mesophases by synchrotron small-angle scattering
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  • Block copolymers made of polystyrene and fluorinated blocks represent a new class of polymers with a very strong incompatibility between the two blocks. They exhibit new stable block copolymer mesophases which are not considered in the phase diagrams of diblock copolymers in the strong and super-strong segregation regime. The solid-state structures of two polymers with different compositions are characterized by synchrotron small-angle X-ray scattering and transmission electron microscopy, thus proving the existence of a quadratically perforated layer phase and a 2D phase of sanidically degenerated cylinders.
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  • 42413
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  • © EDP Sciences, 1998
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  • EDP Sciences
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