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Reactivity of ruthenium trihydrides with Broensted and Lewis acids. X-ray crystal structures of {Cp*Ru[C6H9P(C6H11)2]}BF4 and {{Cp*RuH[P(C6H11)3]}(.mu.-H)2Cu(.mu.-Cl)}2. Evidence for exchange coupling between two hydrogen atoms
Synthesis and X-ray Structure of [(.eta.5-C5Me5)Ti(.mu.3-O)3{Rh(COD)}3] (COD = Cycloocta-1,5-diene). Organometallic Approach to Strong Metal-Support Interaction in Heterogeneous Catalysis
First Observation in a Niobium Complex of the Rotation of a Coordinated H-D Molecule Blocked at the NMR Time Scale
Formation of .eta.2-iminoacyl compounds by protonation of a ketenimine ligand in bis((trimethylsilyl)cyclopentadienyl) compounds of niobium. Molecular structures of [Nb(.eta.5-C5H4SiMe3)2Cl(.eta.2(C,N)-EtPhHCCNPh)]+BF4- and [Nb(.eta.5-C5H4SiMe3)2F(.eta.2(C,N)-Ph2HCCNPh)]+BF4-
Synthesis of Coinage Metal Cation Adducts of Nb(C5H4SiMe3)2H(CO). X-ray Crystal Structure of [{Nb(C5H4SiMe3)2(CO)}2(.mu.-H)2Cu]PF6
Synthesis, Spectroscopic Properties, and X-ray Crystal Structure of {[Nb(C5H3[SiMe3]2)2H3]2Au}+, a Complex Showing Large Quantum Mechanical Exchange Couplings
Exchange Coupling in Niobocene Trihydrides, Nb(C5H3RR‘)2H3, and Their Adducts withCopper Triad Cations, [{Nb(C5H3RR‘)2H3}2M]+ (R = R‘ = H; R = H, R‘= SiMe3;R = R‘ = SiMe3; M = Cu, Ag, Au)
Zirconium Alkyl Thiolate Complexes: Synthesis andReactivity. Molecular Structures of[Zr(η5-C5H5)2(η2-C6H7N2S)(Me)] and[Zr(η5-C5H5)2(η1-C6H7N2S)(η2-CH3CNXylyl)] (Xylyl =2,6-Dimethylphenyl)
Niobocene Alkyne Complexes: Synthesis andCharacterization of Neutral and Cationic d2 MetalAlkyne Derivatives. X-ray Crystal Structure of[Nb(η5-C5H4SiMe3)2(η2(C,C)-HC⋮CPh)(CH2Ph)]
Synthesis and Characterization of New Alkyl−CarbonDioxide Compounds and the First NeutralAcyl−Carbonyl Niobocene Complexes
Early-Transition-Metal Ketenimine Complexes: Synthesis, Reactivity, and Structure ofKetenimine-Containing Titanocene and ZirconoceneComplexes
New Monocyclopentadienyl Complexes of Titanium(IV)and Zirconium(IV) with Chelating Pyrimidinethiolate,Oxypyrimidine, and Oxypyridine Ligands. MolecularStructure of [Zr(η5-C5Me5)(η2-O,N-ON2C6H7)3]
Niobium and Zirconium Complexes IncorporatingAsymmetrically Substituted ansa Ligands. X-ray CrystalStructures of [Me2Si(η5-C5Me4)(η5-C5H3R)]Nb(NtBu)Cl(R = Me, iPr) and [Me2Si(η5-C5Me4)(η5-C5H3R)]ZrCl2 (R =H, Me)
Synthesis and Reactivity of Novel Niobocene ComplexesContaining Allyl or 1-Azaallyl Ligands. X-ray CrystalStructure of [Li{η3-N(SiMe3)C(tBu)CH2}]3
Rhodium and Iridium Hydroxide Complexes[M(μ-OH)(COD)]2 (M = Rh, Ir) as Versatile Precursors ofHomo and Early−Late Heterobimetallic Compounds.X-ray Crystal Structures of Cp*Ta(μ3-O)4[Rh(COD)]4 (Cp*= η5-C5Me5) and [Ir(2-O-3-CN-4,6-Me2-C5HN)(COD)]2
Water-Soluble Organometallic Complexes of Tantalum: Can Alkyland Aqua Ligands Coexist in Its Coordination Sphere?
Preparation of New Monoanionic “Scorpionate” Ligands: Synthesis andStructural Characterization of Titanium(IV) Complexes Bearing ThisClass of Ligand
First Complexes of Scandium and Yttrium with NNO and NNSHeteroscorpionate Ligands
Building Layer-by-Layer a Bis(dithiocarbamato)copper(II)Complex on Au{111} Surfaces
ansa-Niobocene Complexes: Synthesis andCharacterization of Novel Complexes[Me2Si(η5-C5H4)2]NbCl2 and[Me2Si(η5-C5H4)2]NbCl(RC⋮CR) (R = Me, Ph). X-rayCrystal Structure of [Me2Si(η5-C5H4)2]NbCl(MeC⋮CMe)
Cationic Titanium Complexes Containing Alkoxide and CarboxylatePincer Ligands; Noninnocent Role of the Anionic Moieties inTheir Reactivity
Preparation, Characterization, and Reactivity of Tantalum Complexes Containing Tridentate Bis(phenolato) [OSO]-Type Ligands
Synthesis and Characterization of Palladium(II) Complexes with New Polydentate NitrogenLigands. Dynamic Behavior Involving Pd−N Bond Rupture. X-ray Molecular Structure of[{Pd(η3-C4H7)}2(Me-BPzTO)](4-MeC6H4SO3) [Me-BPzTO =4,6-Bis(4-methylpyrazol-1-yl)-1,3,5-triazin-2-olate]
Synthesis and Spectroscopic Properties of DihydrogenIsocyanide Niobocene [Nb(η5-C5H4SiMe3)2(η2-H2)(CNR)]+Complexes. Experimental and Theoretical Study of theBlocked Rotation of a Coordinated Dihydrogen
Studies on the Insertion Reactions of Activated Alkynesinto Nb−H Bonds in Hydride−Niobocene Complexes.X-ray Crystal Structures ofNb(η5-C5H4SiMe3)2(H)[η2-RO2C(H)C(H)CO2R](R = Me or tBu)
Synthesis and Characterization of New NiobiumHydridotris(3,5-dimethylpyrazol-1-yl)borato Complexes
Reactivity of Zirconium Complexes IncorporatingAsymmetrically Substituted ansa Ligands and Their Useas Catalysts in Olefin Polymerization. X-ray CrystalStructures of [Me2Si(η5-C5Me4)(η5-C5H3R)]ZrCl2(R = Et, iPr)
Synthesis and Reactivity of MonocyclopentadienylTantalum Complexes with Pincer Dialkoxide Ligands
New Niobocene Alkyne Complexes: Synthesis andCharacterization of Neutral and Cationic NiobiumComplexes with Functionalized Alkynes. X-ray CrystalStructure of [Nb(η5-C5H4SiMe3)2(Cl)(η2(C,C)-R1C⋮CR2)](R1 = C⋮CPh, R2 = Ph (2b); R1 = CH2CHC(CH3)2, R2 =Ph (3b))
New Monocyclopentadienyl Complexes of Tantalum withDithiolate Ligands. Crystal and Molecular Structures ofCp*TaCl2(SCH2CH2)2S, Cp*TaMe2(SCH2CH2)2O,Cp*TaMe2(SCH2CH2)2S, andCp*Ta(xylylNC(Me)2CNxylyl)(SCH2CH2)2O (Cp* =η5-C5Me5)
Polymerization of Ethylene by the ElectrophilicHeteroscorpionate-Containing Complexes[TiCl3(bdmpza)] and [TiCl2(bdmpza){O(CH2)4Cl}](bdmpza = Bis(3,5-dimethylpyrazol-1-yl)acetate)
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