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Lithium-7, silicon-29, tin-119, and lead-207 NMR studies of phenyl-substituted Group 4 anions
Bond scission in sulfur compounds. 13. Reactivity-selectivity correlations. 3. The .alpha. effect at saturated carbon. Reactivity studies of methyl phenyl sulfates with nucleophiles
Rate-limiting proton transfer in .sigma.-complex formation between 1,3,5-trinitrobenzene and N-methylaniline in dimethyl sulfoxide. The differing reactivities of aromatic and aliphatic amines in .sigma.-complex formation and in SNAr processes
Hydrogen exchange studies. 17. Base-catalyzed isotopic exchange of molecular hydrogen. 5. The potassium anilide-aniline system
NMR studies of phenylsilyl anions. Evaluation of ion pairing and charge distribution
Hydrogen exchange studies. VII. Isotopic exchange of molecular hydrogen in dimethyl sulfoxide-water mixtures under base cataysis
Carbanion mechanisms. 9. Spectrophotometric study of triphenylmethyl alkali metal salts. Contact and solvent-separated ion pairs in ethereal solvents
Reactivity-selectivity correlations. 2. Reactivity of alkyl aryl sulfates toward oxygen nucleophiles and the reactivity-selectivity principle
Mechanistic studies in strong acids. 15. 4-[(3,4-Dimethoxyphenyl)azo]pyridine: two different pathways in the acid hydrolysis of the two methoxy groups
Reactivity-selectivity correlations. 4. The .alpha. effect in SN2 reactions at sp3 carbon. The reactions of hydrogen peroxide anion with methyl phenyl sulfates
Origin of the Bell-Shaped .alpha.-Effect-Solvent Composition Plots. pKa-Solvent Dependence of the .alpha.-Effect at a Phosphorus Center
Metal-ion catalysis in nucleophilic displacement reactions at carbon, phosphorus, and sulfur centers. 5. Alkali-metal ion catalysis and inhibition in the reaction of p-(trifluoromethyl)phenyl methanesulfonate with ethoxide ion
Initial-state and transition-state solvent effects on reaction rates and the use of thermodynamic transfer functions
Catalysis of Isotopic Hydrogen Exchange in 1-Methylimidazole by Cr(III)
Reaction pathways in the formation of the 1,3,5-trinitrobenzene-anilide .sigma. complex from aniline and the 1,3,5-trinitrobenzene-methoxide .sigma. complex
Base-catalyzed isotopic exchange of molecular hydrogen. 4. Hydrogen isotope effects in the dimethyl sulfoxide-water system
Hydrogen Exchange in Benzyl Methyl Sulfoxide. Kinetic and Spectroscopic Nonequivalence of Methylene Protons
Inversion of kinetic and thermodynamic preferences in Meisenheimer complex formation: regioselectivity in the reaction of 2,4,6-trimethylphenoxide ion with 2,4,6-trinitroanisole and the importance of stereoelectronic factors
Superacidifiers: Assessing the Activation and the Mode ofCharge Transmission of the ExtraordinaryElectron-Withdrawing SO2CF3 and S(O)(NSO2CF3)CF3Substituents in Carbanion Stabilization
The Origin of the α-Effect: Dissection of Ground-State andTransition-State Contributions
Solvent Effect on the α-Effect: Ground-State versusTransition-State Effects; a Combined Calorimetric and KineticInvestigation
Concerning the Denticity of the Dimethylsulfinyl Anion inMeisenheimer Complexation
Alkali Metal Ion Catalysis and Inhibition in NucleophilicDisplacement Reactions at Phosphorus Centers: Ethyl and MethylParaoxon and Ethyl and Methyl Parathion
Thermal Racemization of Substituted Indolinobenzospiropyrans: Evidence of Competing Polar and Nonpolar Mechanisms
Ground-State versus Transition-State Effects on theα-Effect as Expressed by Solvent Effects
Acceleration of Nucleophilic Attack on anOrganophosphorothioate Neurotoxin, Fenitrothion, byReactive Counterion Cationic Micelles. Regioselectivity asa Probe of Substrate Orientation within the Micelle
Alkaline Degradation of the Organophosphorus Pesticide Fenitrothionas Mediated by Cationic C12, C14, C16, and C18 Surfactants
Biomolecule−Mercury Interactions: Modalities of DNA Base−Mercury BindingMechanisms. Remediation Strategies
Modulation of the Spiropyran−Merocyanine Reversionvia Metal-Ion Selective Complexation: Trapping of the“Transient” cis-Merocyanine
Micellar Catalyzed Degradation ofFenitrothion, an OrganophosphorusPesticide, in Solution and Soils
Metal Ion Effects in IsotopicHydrogen Exchange inBiologically ImportantHeterocycles
Reactions of Oximate α-Nucleophiles with Esters: Evidence from SolvationEffects for Substantial Decoupling of Desolvation and Bond Formation
Enhanced Bistability of a Photochromic Microparticle in Condensed Medium
Reinterpretation of Curved Hammett Plots in Reaction ofNucleophiles with Aryl Benzoates: Change in Rate-DeterminingStep or Mechanism versus Ground-State Stabilization
Elucidating the Mechanisms of Acidochromic Spiropyran-Merocyanine Interconversion
Solvent Effect on the α-Effect for the Reactions of Aryl Acetateswith Butane-2,3-dione Monoximate and p-Chlorophenoxide inMeCN−H2O Mixtures
Degradation of the Pesticide Fenitrothion as Mediated by CationicSurfactants and α-Nucleophilic Reagents
Degradation and Sorption of Pirimiphos-methyl in Two NigerianSoils
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