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Synthesis of Base-Free Cationic Zirconium Methyl and Benzyl Complexes. The Crystal and Molecular Structure of {C5H3(SiMe3)2-1,3}2ZrMe(.mu.-Me)B(C6F5)3
Synthesis of Low-Coordinate Chalcogenolato Complexes of Zinc with O, N, S, and P Donor Ligands. Molecular and Crystal Structures of Zn(S-t-Bu3C6H2-2,4,6)2(L) (L = NC5H3Me2-2,6, PMePh2), Zn(Se-t-Bu3C6H2-2,4,6)2(OSC4H8) and Zn(S-t-Bu3C6H2-2,4,6)2(N-methylimidazole)2
Three-coordinate thiolato complexes of zinc: solution and solid-state structures and EHMO analysis of the bonding pattern of [Zn(S-tert-Bu3C6H2-2,4,6)2]2
Synthesis, Structures, and Reactivity of Weakly Coordinating Anionswith Delocalized Borate Structure: The Assessment of Anion Effectsin Metallocene Polymerization Catalysts
Zirconocene-Catalyzed Propene Polymerization: AQuenched-Flow Kinetic Study
Anionic ansa-Zirconocenes withPentafluorophenyl-Substituted Borato Bridges
Versatile Coordination Behavior of Aryl-SubstitutedPhosphiniminate and Phosphoranate Anions: Synthesisand Structural Characterization of Lithium Complexeswith η0, η1, and η6-Arene Coordination
B(C6F5)3 as C6F5 Transfer Agent in Zirconium Chemistry: Borole Sandwich and Borole-Bridged Triple-DeckerComplexes
Construction of a Borole Ligand from CoordinatedDiene and B(C6F5)3 via Successive C−H ActivationSteps: A Case of Catalyst Self-Activation
New Bulky Allyl Complexes of Lanthanide Metals: Roleof Alkali-Metal Cations in Controlling Solid-State andSolution Assemblies in Precatalysts
Active Intermediates in Ethylene Polymerization overTitanium Bis(phenoxyimine) Catalysts
Synthetic, Reactivity, and Structural Studies onBorylcyclopentadienyl Complexes of Titanium: New CpBTitanocene Complexes with C−B−Cl, C−B−O, andC−B−N Bridges (CpB = η5-C5H4B(C6F5)2)
Structural Characterization of a Cationic Zirconocene Dimethylaniline Complex and Related Catalytically Relevant Species
Isobutene Polymerization and Isobutene-Isoprene CopolymerizationCatalyzed by Cationic Zirconocene Hydride Complexes
Synthesis, Ion Aggregation, Alkyl Bonding Modes, andDynamics of 14-Electron Metallocenium Ion Pairs[(SBI)MCH2SiMe3+···X-] (M = Zr, Hf): Inner-Sphere (X =MeB(C6F5)3) versus Outer-Sphere (X = B(C6F5)4)Structures and the Implications for “Continuous” or“Intermittent” Alkene Polymerization Mechanisms
Synthesis, Fluxionality, and Propene Insertion Reactionsof Zirconium Boryldiene Complexes with StericallyUndemanding Cp Ligands
[H2N{B(C6F5)3}2]-: A New, Remarkably Stable DiborateAnion for Metallocene Polymerization Catalysts
Sterically Hindered Lanthanide Allyl Complexes andTheir Use as Single-Component Catalysts for thePolymerization of Methyl Methacrylate andε-Caprolactone
Synthesis and Structures of New Mixed-MetalLanthanide/Magnesium Allyl Complexes
Reactivity of Silyl-Substituted Allyl Compounds withGroup 4, 5, 9, and 10 Metals: Routes to η3-Allyls,Alkylidenes, and sec-Alkyl Carbocations
Activation of Bis(pyrrolylaldiminato) and(Salicylaldiminato)(pyrrolylaldiminato) Titanium PolymerizationCatalysts with Methylalumoxane
Mono(arene) Complexes of Thallium(I) Supported by a WeaklyCoordinating Anion
Thallium(I) Sandwich, Multidecker, and Ether ComplexesStabilized by Weakly-Coordinating Anions: A Spectroscopic,Structural, and Theoretical Investigation
Isolation and Structure of [HC{CH(SiMe3)(SnMe3)}2]+: A Remarkably Stablesec-Alkyl Cation
Evidence for Mixed-Ion Clusters in Metallocene Catalysts: Influence onLigand Exchange Dynamics and Catalyst Activity
Monocyclopentadienyl Bis(phenoxo-imino) ZirconiumComplexes as Precatalyst Species for OlefinPolymerization. Stereospecific Methylation of an IminoGroup with Formation of a Zirconium−amido Bond
Ligand Transfer Reactions of Mixed-Metal Lanthanide/MagnesiumAllyl Complexes with β-Diketimines: Synthesis, Structures, andRing-Opening Polymerization Catalysis
Synthesis, Characterization, and Reactivity ofansa-Bis(allyl) Lanthanide Complexes, a New Class ofSingle-Component Methyl Methacrylate PolymerizationCatalysts
Ligand Mobility and Solution Structures of the Metallocenium Ion Pairs [Me2C(Cp)(fluorenyl)MCH2SiMe3+···X−] (M = Zr, Hf; X = MeB(C6F5)3, B(C6F5)4)
1H and 13C NMR Spectroscopic Study of Titanium(IV)Species Formed by Activation of Cp2TiCl2 and[(Me4C5)SiMe2NtBu]TiCl2 with Methylaluminoxane (MAO)
Formation and Structures of Hafnocene Complexes in MAO- and AlBui3/CPh3[B(C6F5)4]-Activated Systems
Synthesis, Structures, and Ring-Opening PolymerizationReactions of Substituted Cyclopentadienyl Complexes ofZinc
New Bis(allyl)(diketiminato) and Tris(allyl) LanthanideComplexes and Their Reactivity in the Polymerization ofPolar Monomers
Synthesis and Crystal Structure of Ethyl Zinc Chloride
Zinc(II) η1- and η2-Toluene Complexes: Structure and Bonding inZn(C6F5)2·(toluene) and Zn(C6F4-2-C6F5)2·(toluene)
Reactions of Zinc Dialkyls with (Perfluorophenyl)boronCompounds: Alkylzinc Cation Formation vs C6F5Transfer
Novel Zinc and Magnesium Alkyl and Amido Cations forRing-Opening Polymerization Reactions
New sterically hindered manganese selenolato complexes. Isolation and structural characterization of a reaction intermediate, [Mn{N(SiMe3)2}(.mu.-SeC6H2-isoPr3-2,4,6)(THF)]2
Synthesis and structure of zirconium complex [Me2C(C5H4)(Flu)Zr(.mu.-H)Cl]2, an .eta.3:.eta.5-bonded ansa-metallocene
Triple-decker complexes. 8. Triple-decker sandwiches. Syntheses, reactivity, electrochemistry, and x-ray crystal and electronic structures of bis(cyclopentadienylmetal)-.mu.-1,3-diborolenyl complexes with 29-34 valence electrons
Cationic alkylbis(cyclopentadienyl)titanium complexes. Synthesis, reactions with carbon monoxide and tert-butyl isocyanide, and the structure of [Cp2Ti[.eta.2-C(Me)NBu-tert](CNBu-tert)]BPh4.MeCN
Synthesis and Reactivity of New Mono(cyclopentadienyl)zirconium and -hafnium Alkyl Complexes. Crystal and Molecular Structure of [{C5H3(SiMe3)2}HfMe2(.eta.6-toluene)][BMe(C6F5)3]
Base-free cationic zirconium benzyl complexes as highly active polymerization catalysts
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An Introduction to the Review by Barnard in This Issue of Organometallics
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