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of
Are carbenium ions stabilized or destabilized by .alpha.-silyl substitution? The solvolysis of 2-(trimethylsilyl)-2-adamantyl p-nitrobenzoate
Theoretical study of the isomeric cyclopropylidenemethyl and 1-cyclobutenyl cations, unusually stable vinyl cations
Importance of electronic geminal interactions in solvolysis reactions. Application to the determination of the .alpha.-silyl effect on carbonium ion stability
Additions and Corrections - α-Silicon-Substituted Vinyl Cations. A Theoretical ab Initio Investigation.
Stabilization of perpendicular olefins. The structures and rotational barriers of singlet and triplet 1,1-dilithioethylenes
Dilithium Derivative of Tetraphenylsilole: An .eta.1-.eta.5 Dilithium Structure
The .PI. and .SIGMA.N electronic states of the succinimidyl radical. Can nitrogen-centered radicals have .SIGMA.N ground states? An ab initio study
A theoretical survey of singly bonded silicon compounds. Comparison of the structures and bond energies of silyl and methyl derivatives
A theoretical survey of unsaturated or multiply bonded and divalent silicon compounds. Comparison with carbon analogs
Structure and conformation of heterocycles. 16. Probing the anomeric effect. Trimethylsilyloxy and tert-butoxy substituents in 1,4-dioxane derivatives: theory vs. experiment
Substituent effects on the geometries and energies of the silicon-silicon double bond
Triple Bonds to Silicon. Relative Stabilities and Energy Barriers Separating Silanitriles and Silaisonitriles. An ab Initio Study
Vinylic cations from solvolysis. XXI. Solvent effects on the external ion return and the internal return in several vinylic solvolyses
Stabilization of planar tetracoordinate carbon
Vinylic cations from solvolysis. 29. Solvolysis of 9-(.alpha.-bromoarylidene)anthrones as a probe to the reactivity-selectivity relationship in solvolysis reactions
Bimolecular substitution at carbon in neopentyl-like silylcarbinyl sulfonates
Single-crystal molecular structure determinations and theoretical calculations on alkynyl sulfonate and carboxylate esters
Electronic Spectra of Ethynyl- and Vinylsilylenes: Experiment and Theory
Remote inductive effects in the solvolysis of secondary and tertiary 2-norbornyl derivatives. Evidence for nonclassical stabilization of the 2-norbornyl cation
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