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Dimeric iron(III) complex containing two ethyl mercaptide and two ethyl thioxanthate groups as bridging ligands
Mixed-valence coinage metal clusters with 1,1-thioperthio ligands. Syntheses and molecular structures of the copper and gold [Cu4L3]2-, [Cu5L4]-, and [AuCu4L4]- anions (L = 1,1-dicarbo-tert-butoxyethylene-2,2-thioperthiolate). A geometrically-locked, charge-separated valence state in the [Cu5L4]- anion
Bernstein's bond length-bond order relation is applied to carbon-nitrogden, carbon-oxygen, and nitrogen-oxygen bonds in metal complexes
Dinuclear iron-molybdenum-sulfur complexes containing the FeS2Mo core. Syntheses, ground-state electronic structures and crystal and molecular structures of the [(C6H5)4P]2[(C6H5S)2FeS2MoS2], [(C2H5)4N]2[(C6H5S)2FeS2WS2], and [(C6H5)4P]2[(S5)FeS2MS2] (M = Mo, W) complexes
Syntheses and Structural Characterization of a New Class of Double Cubanes That Contain MoFe3S4 Subunits and Molybdenum-Coordinated, Bridging Mercapto-Carboxylate Ligands. Effective Catalysts for the Reduction of Hydrazine to Ammonia
Chemistry of the copper-dithiooxalate complexes. Synthesis of a new carbonyl sulfide complex
Dimerization of the molybdenum complex [(SO4)Mo(O)(.mu.-S)2Mo(O)(SO4)]2- dianions stabilized by a quadruply bridging sulfate ligand and intramolecular hydrogen bonding by the [(CH3)2NH2]+ cations. Structures of the [(CH3)2NH2]6-x(Et4N)x[{(SO4)Mo(O)(.mu.-S)2Mo(O)(SO4)}2(SO4)] aggregates (x = 1, 2, 2.5)
Activation and cleavage of the carbon-sulfur bond in niobium tert-butanethiolato complexes. Syntheses and structural characterizations of the tetrahedral and trigonal bipyramidal [Ph4P][NbV(S)2(tert-BuS)2] and [Et4N][NbV(S)(tert-BuS)4] complexes
Structural Characterization and Reactivity Properties of a New Class of Fe/Mo/S Double Cubanes with Mo-Bound S-.mu.2-.eta.1,O-.eta.1 Mercapto Carboxylate Ligands. New Catalysts for the Reduction of Hydrazine to Ammonia and Implications Regarding the Function of Nitrogenase
Crystal and molecular structure of bis(ethyl thioxanthato)-.mu.-bis(ethyl thioxanthato)-.mu.'-bis(ethylthio)diiron(III)
Multifunctional macrocyclic ligands. Synthesis and characterization of nickel(II) and cobalt(II) macrocyclic-catechol complexes and their dimeric, antiferromagnetically coupled, semiquinone derivatives
Uncharged Mixed-Ligand Clusters with the [Fe4S4]+ and [Fe4S4]2+ Cores. Synthesis, Structural Characterization, and Properties of the Fe4S4X(tBu3P)3 (X = Cl, Br, I) and Fe4S4(SPh)2(tBu3P)2 Cubanes
Synthesis, structural characterization, and properties of new single and double cubanes containing the MoFe3S4 structural unit and molybdenum-bound polycarboxylate ligands. Clusters with a molybdenum-coordination environment similar to that in the iron-molybdenum cofactor of nitrogenase
The catalytic reduction of hydrazine to ammonia by the MoFe3S4 cubanes and implications regarding the function of nitrogenase. Evidence for direct involvement of the molybdenum atom in substrate reduction
Square-planar sulfur complexes. VI. Reactions of bases with xanthates, dithiocarbamates, and dithiolates of nickel(II)
Use of preassembled iron/sulfur and iron/molybdenum/sulfur clusters in the stepwise synthesis of potential analogs for the Fe/Mo/S site in nitrogenase
Catalytic Reduction of Hydrazine to Ammonia by the VFe3S4 Cubanes. Further Evidence for the Direct Involvement of the Heterometal in the Reduction of Nitrogenase Substrates and Possible Relevance to the Vanadium Nitrogenases
A new class of bis(.mu.-aryloxy)-bridged dimers with first-row divalent transition-metal ions. Synthesis and structural characterization of the (Et4N)2[M2Cl4(O-C6H4-p-CH3)2] complexes (M = Mn(II), Fe(II), Co(II), Zn(II), and Cd(II))
Synthesis, structural characterization, and properties of singly bridged double molybdenum-iron cubanes containing two [(Cl4-cat)MoFe3S4Cl3]2- subunits and hydrazine or pyrazine bridges
Tetrahedral complexes containing the Fe(II)S4 core. The syntheses, ground-state electronic structures and crystal and molecular structures of the bis(tetraphenylphosphonium) tetrakis (thiophenolato)ferrate (II) and bis (tetrapheny lphosphonium) bis(dithiosquarato)ferrate (II) complexes. An analog for the active site in reducd rubredoxins (Rdred)
Rational Synthesis of High Nuclearity Mo/Fe/S Clusters: The Reductive CouplingApproach in the Convenient Synthesis of (Cl4-cat)2Mo2Fe6S8(PR3)6 [R = Et, nPr, nBu] andthe New [(Cl4-cat)2Mo2Fe2S3O(PEt3)3Cl]·1/2(Fe(PEt3)2(MeCN)4) and(Cl4-cat)2Mo2Fe3S5(PEt3)5 Clusters
Synthesis and Characterization of Sulfur-Voided Cubanes.Structural Analogues for the MoFe3S3 Subunit in theNitrogenase Cofactor
Density Functional Theory Calculations and Exploration of aPossible Mechanism of N2 Reduction by Nitrogenase
A New Function of the (μ3-S) Ligand in an Fe4S4Cluster: Synthesis and Structure of the High-Nuclearity Mo/Fe/S Cluster, Fe(DMF)Cl(Cl4-cat)2-Mo2Fe2S4(PEt3)2ClFe4S4(PEt3)3(CO)6Cl
Synthesis and Structure of Singly Bridged and Doubly Bridged[MoFe3S4] Double Cubanes with Bidentate Phosphine Ligands
Synthesis and Reactivity of a New Octanuclear Iron−Sulfur NitrosylCluster
Metal Clusters as Ligands. Substitution of Fe Ions in Fe/Mo/S Clustersby Thiophilic CuI Ions
Normal-Mode Analysis of FeCl4- and Fe2S2Cl42- via VibrationalMössbauer, Resonance Raman, and FT-IR Spectroscopies
Borohydride, Azide, and Chloride Anions As Terminal Ligands onFe/Mo/S Clusters. Synthesis, Structure and Characterization of[(Cl4-cat)(PPr3) MoFe3S4(X)2]2(Bu4N)4 and [(Cl4-cat)(PPr3)MoFe3S4(PPr3)(X)]2(Bu4N)2 (X = N3-, BH4-, Cl-) Double-Fused Cubanes. NMRReactivity Studies of [(Cl4-cat)(PPr3) MoFe3S4(BH4)2]2(Bu4N)4
Systematic Synthesis of Heterometallic Ni/Fe/S and Cu/Fe/S Clusters with aPentlandite-like M8S6 Core
Macrocyclic catechol complexes as ligands in the synthesis of heterometallic supramolecules
Synthesis and Structural Characterization of the New Mo2Fe6S8(PR3)6(Cl4-cat)2 Clusters. Double Cubanes Containing Two Edge-Linked [MoFe3S4]2+ Reduced Cores
Metastable iron/sulfur clusters. The synthesis, electronic structure, and transformations of the [Fe6S6(L)6]3- clusters (L = Cl-, Br, I-, RS-, RO-) and the structure of [(C2H5)4N]3[Fe6S6Cl6]
Fe-M-S complexes derived from MS42- anions (M = molybdenum, tungsten) and their possible relevance as analogs for structural features in the molybdenum site of nitrogenase
Use of [MoFe3S4]3+ Single Cubanes in the Catalytic Reduction of Acetylene to Ethylene and Ethane. Identification of Molybdenum and Iron Atoms as Catalytic Sites during Substrate Reduction and Implications for Nitrogenase Action
Crystal and molecular structure of thio-p-toluoyldisulfidobis (dithio-p-toluato)iron(III)
Single and double MoFe3S4 cubanes with molybdenum-coordinated polycarboxylate ligands. Syntheses and structural characterization of (Et4N)4{[MoFe3S4Cl4]2(.mu.-C2O4)} and (Et4N)3([MoFe3S4Cl4(C2O4)] clusters
Reactions of the molybdenum-sulfur double bond in the [(Cp)Mo(O)(.mu.-S)2Mo(O)(S)]- complex with sulfur dioxide. An proton NMR study and the synthesis and structural characterization of [(Cp)Mo(O)(.mu.-S)2Mo(O)(L)]- complexes containing SO2-derived sulfite, thiosulfate, and sulfate bidentate chelating ligands
Functional analogs for the reduction of certain nitrogenase substrates. Are multiple sites within the Fe/Mo/S active center involved in the 6e- reduction of N2?
Stepwise synthesis and structural characterization of the molybdenum-iron-sulfur {[MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)2}6- and {[MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)(.mu.2-OH}5- doubly bridged double cubanes obtained by the coupling of [MoFe3S4] clusters
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