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Sol−Gel Reaction of Porphyrin-Based Superstructures in the OrganogelPhase: Creation of Mechanically Reinforced Porphyrin Hybrids
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We have demonstrated that a one-dimensional molecular assembly created by an H-aggregated porphyrin·Cu(II) stack can be immobilized, without a morphological change, by sol−gel polycondensation of the peripheral triethoxysilyl groups. The resultant gel prepared according to this flowchart has gained a very high thermal stability as well as a unique mechanical strength.
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