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Intramolecular Arene Hydroxylation versus Intermolecular Olefin Epoxidationby (μ-η2:η2-Peroxo)dicopper(II) Complex Supported by Dinucleating Ligand
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dcterms:abstract
A discrete (μ-η2:η2-peroxo)Cu(II)2 complex, [Cu2(O2)(H-L)]2+, is capable of performing not only intramolecular hydroxylation of a m-xylyl linker of a dinucleating ligand but also intermolecular epoxidation of styrene via electrophilic reaction to the CC bond and hydroxylation of THF by H-atom abstraction.
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