. . . . "The simple and efficient asymmetric synthesis of 3\u00B0-carbamines 7 from N-TMS enamines (3) and either enantiomeric form of \u03B2-allyl-10-(phenyl)-9-borabicyclo[3.3.2]decane (1) is reported. The high reactivity (<1 h, \u221278 \u00B0C) and enantioselectivity (60\u221298% ee) of these substrates can be attributed to the fact that the complexation of 3 with 1 facilitates its isomerization to the corresponding syn-N-TMS ketimine complex from which allylation can occur. In addition to providing the homoallylic amines 7 with predictable stereochemistry, the procedure also permits the efficient recovery of the chiral boron moiety (50\u221265%) as air-stable crystalline pseudoephedrine complexes 8, which are directly converted back to 1 with allylmagnesium bromide in ether (98%)." . . . . . . . . . . . "Nonracemic 3\u00B0-Carbamines from the Asymmetric Allylboration ofN-Trimethylsilyl Ketimines with B-Allyl-10-phenyl-9-borabicyclo[3.3.2]decanes" .