About: Copper Complexes for Fluorescence-Based NO Detection in AqueousSolution

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_35/w
Subject	Communication
Title	Copper Complexes for Fluorescence-Based NO Detection in AqueousSolution
has manifestation of work	http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_35/101021ja053150o/m/print http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_35/101021ja053150o/m/web
related by	http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_35/101021ja053150o/authorship/1 http://hub.abes.fr/acs/periodical/jacsat/2005/volume_127/issue_35/101021ja053150o/authorship/2
Author	Lim Mi Hee Lippard Stephen J.
Abstract	Two copper(II) complexes containing dansylated ligands were investigated as turn-on fluorescence-based nitric oxide (NO) sensors. Upon addition of NO (g), the quenched fluorescence of both complexes was restored in both organic and buffered aqueous solutions, which is caused by the formation of a diamagnetic Cu(I) species and protonation of the sulfonamide functionality of the ligands. The NO detection limit of these Cu(II) complexes is 10 nM.
article type	rapid-communication
is part of this journal	Journal of the American Chemical Society

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