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Atropisomerism of the C-1−C‘-1 Axis of 2,2‘,8,8‘-Unsubstituted1,1‘-Binaphthyl Derivatives
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A Facile Synthesis of Naturally OccurringAminopeptidase Inhibitor Tyromycin A
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DFT-Based Quantitative Prediction ofRegioselectivity: Cycloaddition ofNitrilimines to Methyl Propiolate
A Biomimetic Approach to Dihydrobenzofuran Synthesis
Oxidation of Nitrobenzylic Carbanions with Dimethyldioxirane.New Synthesis of Quinomethanes and Nitrobenzylic Carbinols.First Examples of Methylation of Carbanions withDimethyldioxirane
Kinetics of the Thiazolium Ion-Catalyzed Benzoin Condensation
Metal-Promoted Allylation, Propargylation, or Allenylation ofAzetidine-2,3-diones in Aqueous and Anhydrous Media.Application to the Asymmetric Synthesis of DenselyFunctionalized 3-Substituted 3-Hydroxy-β-lactams
Intramolecular Cyclizations of IminesBearing the2-(Thiomethyl)-3-trimethylsilyl-1-propenylTerminator. An Efficient New Procedurefor the Stereocontrolled Synthesis ofFunctionalized Pyrrolidine Derivatives
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Acid-Catalyzed Hydrolysis andLactonization of α2,8-Linked OligosialicAcids
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Iron-Catalyzed Reaction of PropargylSulfides and Trimethylsilyldiazomethane
Total Synthesis of Rutamycin B, a Macrolide Antibiotic fromStreptomyces aureofaciens
Supramolecular Assemblies between Macrocyclic PorphyrinHexamers and Star-Shaped Porphyrin Arrays
Transmembrane Ion Channels Constructed of Cholic AcidDerivatives
Synthesis and Solution Conformational Analysis of2,3-Anhydro-3-C-[(1R)-2,6-anhydro-1-deoxy-1-fluoro-d-glycero-d-gulo-heptitol-1-C-yl]-β-d-gulo-furanose: First Example of aMonofluoromethylene-Linked C-Disaccharide
Transition States and Mechanisms of the Hetero-Diels−AlderReactions of Hyponitrous Acid, Nitrosoalkanes, Nitrosoarenes,and Nitrosocarbonyl Compounds
Induction of Diastereoselectivity in Fe(II) Tris(aminoacid−bipyridine) Complexes
Nucleophilicity toward Ketenes: Rate Constants for Addition ofAmines to Aryl Ketenes in Acetonitrile Solution
Development of a New Carbon−Carbon Bond Forming Reaction.New Organic Chemistry of Sulfur Dioxide. AsymmetricFour-Component Synthesis of Polyfunctional Sulfones
Role of Hydrogen Bonding in the Oxidation of Thianthrene5-Oxide with Peroxy Acids
Organometallic Dehydro[14]annulenes Containing Vollhardt'sCyclobutadiene: Are CpCo-Complexed Cyclobutadienes MoreAromatic than Benzene?
Synergic Effect of Vicinal Stereocenters in [3 + 2] Cycloadditionsof Carbohydrate Azadipolarophiles and Mesoionic Dipoles: Originof Diastereofacial Selectivity
Two-Carbon Homologation of Aldehydes via Silyl Ketene Acetals.2. Study of the Stereochemical Control in the Formation of(E)-Alkenoic Acids
Tuning Lipase Enantioselectivity in Organic Media UsingSolid-State Buffers
C−H Bond Activation in Dense CarbonDioxide: Rhodium-Catalyzed MethaneCarbonylation and AlkaneDehydrogenation
Semisynthesis of D-Ring Modified Taxoids: Novel ThiaDerivatives of Docetaxel
Generation of Cyclopentadienones from2-Bromocyclopentenones
Double Carbonylation of Aryl Iodides withPrimary Amines under AtmosphericPressure Conditions Using the Pd/PPh3/DABCO/THF System
Stereoselective Nucleophilic Formylation and Cyanation ofα-Alkoxy- and α-Aminoaldehydes
Synthesis of 5-epi-[6-2H2]Valiolone and StereospecificallyMonodeuterated 5-epi-Valiolones: Exploring the Steric Course of5-epi-Valiolone Dehydratase in Validamycin A Biosynthesis
The Solid State and Solution Structure ofHAPyU,,
The Effect of Neighboring 1- and 2-Adamantyl Group Substitutionon the Conformations and Stereodynamics of N-Methylpiperidine.Dynamic NMR Spectroscopy and Molecular MechanicsCalculations1
Intramolecular 1,3-Dipolar Cycloadditions ofNorbornadiene-Tethered Nitrones
A Straightforward Synthetic Entry to the4,9b-Propanopyrrolo[2,3-c]quinolineSystem by a New Reductive Cyclization ofα‘-(2-Nitrophenyl) Enones
A Mild Procedure for the Reduction ofPyridine N-Oxides to Piperidines UsingAmmonium Formate
Nucleophilic Substitution by a Hydroxide Ion at a Vinylic Carbon: Ab Initio and Density Functional Theory Studies onMethoxyethene, 3-Methoxypropenal, 2,3-Dihydro-4H-pyran-4-one,and 4H-Pyran-4-one
C60-Based Triads with Improved Electron-Acceptor Properties: Pyrazolylpyrazolino[60]fullerenes
An Unusual Decarboxylative Maillard Reaction between l-DOPAand d-Glucose under Biomimetic Conditions: Factors GoverningCompetition with Pictet−Spengler Condensation
Phosphinic Acid Pseudopeptides Analogous toGlutamyl-γ-glutamate: Synthesis and Coupling to Pteroyl AzidesLeads to Potent Inhibitors of Folylpoly-γ-glutamate Synthetase
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