| Abstract
| - Iron-assisted SNAr reactions were performed for the first time on solid phase, and a library of 36unsymmetrically substituted phenylpiperazines and phenyl-1,4-diazepanes was synthesized withthis novel strategy. The scope of iron-assisted SNAr reactions on solid phase was investigated, andreactions of representative nucleophiles from groups VI (O, S, and Se) and V (N and P) of theperiodic table were examined. Decomplexation of resin-bound iron complexes was achieved with1,10-phenanthroline under irradiation, thereby overcoming the notorious disadvantages of decomplexation observed in solution-phase chemistry.
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