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Tributylphosphine: A Remarkable Promoting Reagent for theRing-Opening Reaction of Aziridines
Lewis Acid-Activated Chiral Leaving Group: EnantioselectiveElectrophilic Addition to Prochiral Olefins
Dipole-Stabilized Carbanions: A Computational Study ofN-Methylformamide Anion and Methyl N-Methylcarbamate Anion
Synthesis of New Tricyclic Phosphines andPhosphinites by IntramolecularDiels−Alder Reactions of TrivalentPhospholes
An Efficient Convergent Synthesis of Novel AnisotropicAdsorbates Based on Nanometer-Sized and Tripod-ShapedOligophenylenes End-Capped with Triallylsilyl Groups
Reaction of Allylsilanes and Allylstannanes with AlkynesCatalyzed by Electrophilic Late Transition Metal Chlorides
Synthesis of the tRNALys,3 Anticodon Stem-Loop DomainContaining the Hypermodified ms2t6A Nucleoside
Total Synthesis of Two NaturallyOccurring Bicyclo[3.2.1]octanoidNeolignans
1,2-Dioxines as Masked Cis γ-Hydroxy Enones and TheirVersatility in the Synthesis of Highly Substituted γ-Lactones
Synthesis of Novel HeteroaromaticsStructurally Related to EllipticineAlkaloids via Thermolysis ofPyridannulated Enyne−Carbodiimides
Selective Reductions. 59. Effective Intramolecular AsymmetricReductions of α-, β-, and γ-Keto Acids withDiisopinocampheylborane and Intermolecular AsymmetricReductions of the Corresponding Esters withB-Chlorodiisopinocampheylborane
Halo-Enediynes: Probing the Electronic and StereoelectronicContributions to the Bergman Cycloaromatization
Boron-Mediated Aldol Reaction of Carboxylic Esters: Complementary Anti- and Syn-Selective Asymmetric AldolReactions
An Improved Protocol for the Preparationof 3-Pyridyl- and Some Arylboronic Acids
Exploring Stereogenic Phosphorus: Synthetic Strategies forDiphosphines Containing Bulky, Highly Symmetric Substituents
Synthesis of [n]- and [n.n]Cyclophanes by Using Suzuki−MiyauraCoupling
A One-Step Procedure for the Monoacylation of Symmetrical1,2-Diols
Iron-Assisted Nucleophilic Aromatic Substitution on Solid Phase
First Stereoselective Synthesis of2-Deoxy-α-d-ribosyl-1-phosphate: NovelApplication of Crystallization-InducedAsymmetric Transformation
Synthesis of 6H-Dibenzo[b,d]pyran-6-ones from Aryl3-Bromopropenoates via a Sequential One-Pot Procedure Usingthe Sonogashira Coupling−Benzannulation Reaction
Synthesis of Polysubstituted Benzothiophenes andSulfur-Containing Polycyclic Aromatic Compounds via SamariumDiiodide Promoted Three-Component Coupling Reactions ofThiophene-2-carboxylate
Computational Studies of Aliphatic Amine Basicity
Origins of Regioselectivity in the Reactions of α-Lactams withNucleophiles. Two Distinct Acid-Catalyzed Pathways Involving O-and N-Protonation
Unexpected Catalyst for Wittig-Type and DehalogenationReactions
Synthesis of4-Diphosphocytidyl-2-C-methyl-d-erythritoland 2-C-Methyl-d-erythritol-4-phosphate
Variable Strategy toward Carbasugars and Relatives. 4. ViableAccess to (4a-Carbapentofuranosyl)amines,(5a-Carbahexopyranosyl)amines, and Amino Acids Thereof
Chiral Nonracemic α-Alkylidene and α-Silylidene Cyclopentenonesfrom Chiral Allenes Using an Intramolecular AllenicPauson−Khand-Type Cycloaddition
Ring-Opening Reactions of Cyclic Acetals and 1,3-Oxazolidineswith Halosilane Equivalents
Chiral N-Alkyl-2,4,6-triphenylpyridiniums as EnantioselectiveTriplet Photosensitizers. Laser Flash Photolysis and PreparativeStudies
Stereoselective Syntheses of the ThreeIsomers of Ethylene GlycolBis(tropane-3-carboxylate)
Synthetic Applications of o- and p-Halobenzyl Sulfones asZwitterionic Synthons: Preparation of Ortho-SubstitutedCinnamates and Biarylacetic Acids
InBr3-Catalyzed Friedel−Crafts Addition ofIndoles to Chiral Aromatic Epoxides: AFacile Route to Enantiopure IndolylDerivatives
Preparation of7-Alkylamino-2-methylquinoline-5,8-diones
Multiple Dendritic Catalysts for Asymmetric TransferHydrogenation
Boronic Acid Receptors forα-Hydroxycarboxylates: High Affinity ofShinkai's Glucose Receptor for Tartrate
Novel Synthesis of cis-Nickel(II)3-Alkylimino-3-alkyl(oraryl)thio-1-arylpropenethiolates and TheirApplication to the Preparation of5-Aryl-3-(arylthio)isothiazoles
Synthesis of Low-Generation, Aryl-/Alkyl-Type, NonpolarDendrons Carrying Protected Hydroxyalkyl Groups in thePeriphery
New Routes to N-Alkylated Cyclic Sulfamidates
Approach toward the Total Synthesis of Orevactaene. 2.Convergent and Stereoselective Synthesis of the C18−C31 Domainof Orevactaene. Evidence for the Relative Configuration of theSide Chain
Naphthalene Diols: A New Class of Antioxidants IntramolecularHydrogen Bonding in Catechols, Naphthalene Diols, and TheirAryloxyl Radicals
[4 + 2] Cycloaromatization of4-Bis(methylthio)-3-buten-2-one with ActiveMethylene Ketones: A Simple and FacilePhenol Annulation
Solvent Effects on Barrierto Rotation of Enaminonitriles Using Inversion Transfer 1H NMRSpectroscopy and FTIR Spectroscopy.
Rearrangement of Epoxynitriles: AConvenient Homologation of Acyclic andCyclic Ketones to Carboxylic Acids
Total Synthesis of (±)-Momilactone A
Ni-to-Ni+ 3-Ethylene-Bridged Partially Modified Retro-InversoTetrapeptide β-Turn Mimetic: Design, Synthesis, and StructuralCharacterization
Cyclobutenbriarein A, the First Diterpene with aTricyclo[8.4.0.03,6]tetradec-4-ene Ring System Isolated from theGorgonian Briareum asbestinum
Synthesis of [5‘-13C]Ribonucleosides and2‘-Deoxy[5‘-13C]ribonucleosides
Catalytic Oxidations of Steroid Substrates by ArtificialCytochrome P-450 Enzymes
A Simple and Versatile Method for the Synthesis of Acetals fromAldehydes and Ketones Using Bismuth Triflate
Sebastianines A and B, Novel BiologicallyActive Pyridoacridine Alkaloids from theBrazilian Ascidian Cystodytes dellechiajei
Mild and Highly Selective Formyl Protection of Primary HydroxylGroups
A Biomimetic Transformation ofSerratinine into Serratezomine A througha Modified Polonovski Reaction
Mechanistic Study of Stereoselective Gas-Phase Reactions ofPhosphenium Ions with cis- and trans-1,2-Diaminocyclohexanes
Steric Hindrance as a Mechanistic Probe for Olefin Reactivity: Variability of the Hydrogenic Canopy over the IsomericAdamantylideneadamantane/Sesquihomoadamantene Pair(A Combined Experimental and Theoretical Study)
Kottamides A−D: Novel BioactiveImidazolone-Containing Alkaloids from theNew Zealand Ascidian Pycnoclavella kottae
Toward Synthesis of α-Alkyl AminoGlycines (A3G), New Amino AcidSurrogates
Linear Total Synthetic Routes toβ-d-C-(1,6)-Linked Oligoglucoses and Oligogalactoses up to Pentaoses by Iterative Wittig Olefination Assembly.
Ketene-Forming Eliminations from Aryl Phenylacetates Promotedby R2NH/R2NH2+ in Aqueous MeCN. Mechanistic Borderlinebetween E2 and E1cb
Study of Fluorocarbonyls for theBaylis−Hillman Reaction
Theoretical Study of Factors Controlling Rates of Cyclization ofRadical Intermediates from Diallylamine and DiallylammoniumMonomers in Radical Polymerizations
A New Bis(2,2,2-trifluoroethyl)phosphonatefor the Synthesis of Z-UnsaturatedN-Methoxy-N-methylamides
Stereoselective Synthesis of Both syn- and anti-N-tert-AlkylaminesUsing Highly Stereospecific Crotylation of Ketone-DerivedAcylhydrazones with Crotyltrichlorosilanes
Dynamic Kinetic Resolution of Racemic γ-Aryl-δ-oxoesters.Enantioselective Synthesis of 3-Arylpiperidines
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