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À propos de : A New Bis(2,2,2-trifluoroethyl)phosphonatefor the Synthesis of Z-UnsaturatedN-Methoxy-N-methylamides        

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  • A New Bis(2,2,2-trifluoroethyl)phosphonatefor the Synthesis of Z-UnsaturatedN-Methoxy-N-methylamides
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  • The N-methoxy-N-methyl bis(2,2,2-trifluoroethyl)phosphonamide was easily obtained via the Arbuzovreaction with use of commercially available tris(2,2,2-trifluoroethyl)phosphite, 2-bromo-N-methoxy-N-methylacetamide, and KF/alumina. The reaction of bis(2,2,2-trifluoroethyl)phosphonate with several aldehydes demonstrates theversatility of the method, which gives Z-unsaturated amidesin good yields.
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