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Copyright © 2003 American Chemical Society
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Conjugated Macrocycles Related to the Porphyrins. 25. ProtonNMR Spectroscopic Evidence for a Preferred [18]AnnuleneSubstructure in Carbaporphyrins from the Magnitude of Selected4JH,H CHCCH3 Coupling Constants
Practical Synthesis and Elaboration ofMethyl 7-Chloroindole-4-carboxylate
First Synthesis of Methylated Hypocrellinand Its Fluorescent Excited State: ACautionary Tale
A Highly Chemoselective, Diastereoselective, and RegioselectiveEpoxidation of Chiral Allylic Alcohols with Hydrogen Peroxide,Catalyzed by Sandwich-Type Polyoxometalates: Enhancement ofReactivity and Control of Selectivity by the Hydroxy Groupthrough Metal−Alcoholate Bonding
Aminoalkoxide-Mediated Formation andStabilization of Phenylpyridyllithium: Straightforward Access to PhenylpyridineDerivatives
Mild Oxidation of Alcohols witho-Iodoxybenzoic Acid (IBX) in Water/Acetone Mixture in the Presence ofβ-Cyclodextrin
Photoenolization as a Means To Release Alcohols
The pKa of the Internucleotidic 2‘-Hydroxyl Group inDiribonucleoside (3‘→5‘) Monophosphates
Hydroxylamines as Oxidation Catalysts: Thermochemical andKinetic Studies
Dual Nucleophilic Catalysis with DABCO for the N-Methylation ofIndoles
Solid-Phase Synthesis of an A−B Loop Mimetic of the Cε3 Domainof Human IgE: Macrocyclization by Sonogashira Coupling
Mechanism of an Alcohol-Trapping Reaction in the Direct andBenzophenone-Sensitized Photodenitrogenation of aSpiroepoxy-Substituted Azoalkane: Solvent Effects andStereochemical Deuterium Labeling
Stereocontrolled Synthesis of Bicyclic Lactone Derivatives viaTungsten-Mediated [3 + 2] Cycloaddition of Epoxides with aTethered Alkynyl Group
Practical and High-Yield Syntheses ofDihydromorphine fromTetrahydrothebaine and EfficientSyntheses of (8S)-8-Bromomorphide
Rearrangement Pathways of Five-Membered Ring Enlargement inCarbocations: Quantum Chemical Calculations and DeuteriumKinetic Isotope Effects
Novel Radical Compounds Bearing Mesogenic Cores with LongAlkyl Substituents
First Enantioselective Synthesis of Vinyl Oxiranes from Aldehydes and YlidesGenerated from Allyl Halides and Chiral Sulfides.
Development and Conformational Analysis of aPseudoproline-Containing Turn Mimic
Preparation of Nitrogen-Containingπ-Deficient Heteroaromatic GrignardReagents: Oxidative Magnesiation ofNitrogen-Containing π-DeficientHalogenoheteroaromatics UsingActive Magnesium
Highly Efficient Deprotection of AromaticAcetals under Neutral Conditions Usingβ-Cyclodextrin in Water
A Comparison of Linear Optical Properties and Redox Propertiesin Chalcogenopyrylium Dyes Bearing Ortho-Substituted ArylSubstituents and tert-Butyl Substituents
One-Step Highly DiastereoselectiveSynthesis of γ-Aminoalkyl-Substitutedγ-Butyrolactones by an AsymmetricSamarium-Mediated Ketyl−AlkeneCoupling Reaction
Ring Expansions of β-Keto Lactones with Zinc Carbenoids: Syntheses of (+)-Patulolide A and (±)-Patulolide B
Temperature- and Time-Dependent Stereochemical Control inThermally Induced Keto−Ene Cyclizations
Gauging the Significance of Atomic Oxygen [O(3P)] in SulfoxidePhotochemistry. A Method for Hydrocarbon Oxidation
A Short Path Synthesis of [13C/15N] Multilabeled PyrimidineNucleosides Starting from Glucopyranose Nucleosides
ortho-Metalation of Unprotected 3-Bromoand 3-Chlorobenzoic Acids with HinderedLithium Dialkylamides
Conformational Studies by Dynamic NMR. 93. Stereomutation,Enantioseparation, and Absolute Configuration of theAtropisomers of Diarylbicyclononanes
Increased Polymer Length ofOligopeptide-Substituted Polynorborneneswith LiCl
The α-Effect in Methyl Transfers fromS-Methyldibenzothiophenium Fluoroborate to SubstitutedN-Methylbenzohydroxamates
Generation of Chiral Boron Enolates by Rhodium-CatalyzedAsymmetric 1,4-Addition of 9-Aryl-9-borabicyclo[3.3.1]nonanes(B-Ar-9BBN) to α,β-Unsaturated Ketones
UV Band Splitting of Chromogenic Azo-Coupled Calix[4]crownupon Cation Complexation
A Formal [3 + 3] Cycloaddition Reaction. Improved ReactivityUsing α,β-Unsaturated Iminium Salts and Evidence forReversibility of 6π-Electron Electrocyclic Ring Closure of1-Oxatrienes
An Approach to the Synthesis of the Phomoidrides
Synthesis and Reactions of Aminoporphyrazines with AnnulatedFive- and Seven-Membered Rings
A Novel Method for the Determination of Stereochemistry inSix-Membered Chairlike Rings Using Residual Dipolar Couplings
Expeditious Synthesis of New 1,2,3-Thiadiazoles and1,2,3-Selenadiazoles from 1,2-Diaza-1,3-butadienes viaHurd−Mori-Type Reactions
Stereospecific Synthesis ofPolyfunctionalized Carbacephams Inducedby Titanocene(III) Chloride
Structure and Absolute Stereochemistry of Phormidolide, aNew Toxic Metabolite from the Marine Cyanobacterium Phormidium sp.
Studies in Polyphenol Chemistry and Bioactivity. 4. Synthesis ofTrimeric, Tetrameric, Pentameric, and Higher OligomericEpicatechin-Derived Procyanidins Having All-4β,8-InterflavanConnectivity and Their Inhibition of Cancer Cell Growth throughCell Cycle Arrest1
N-Arylation of Aziridines
Total Synthesis and Structure Confirmation of the AnnonaceousAcetogenins 30(S)-Hydroxybullatacin, Uvarigrandin A, and5(R)-Uvarigrandin A (Narumicin I?)
Studies of the Biosynthesis of DTX-5a and DTX-5b by theDinoflagellate Prorocentrum maculosum: Regiospecificity of thePutative Baeyer−Villigerase and Insertion of a Single Amino Acidin a Polyketide Chain
Stable Simple Enols. Self-Catalyzed E/Z-Isomerization of theSterically Crowded 2-(m-Methoxymesityl)-1,2-dimesitylethenol1
A Modular Synthesis of Annonaceous Acetogenins
Cyclic Allene Intermediates in Intramolecular DehydroDiels−Alder Reactions: Labeling and TheoreticalCycloaromatization Studies
A Trifunctional Catalyst for One-Pot Synthesis of Chiral Diols viaHeck Coupling−N-Oxidation−Asymmetric Dihydroxylation: Application for the Synthesis of Diltiazem and Taxol Side Chain
Efficient Desymmetrization of “Pseudo”-C2-Symmetric Substrates: Illustration in the Synthesis of a Disubstituted Butenolide fromArabitol
Calorimetric and Computational Study of Thiacyclohexane1-Oxide and Thiacyclohexane 1,1-Dioxide (Thiane Sulfoxide andThiane Sulfone). Enthalpies of Formation and the Energy of theSO Bond
Brocaenols A−C: Novel Polyketides from aMarine-Derived Penicillium brocae
Conformation of Secondary Amides. A Predictive Algorithm ThatCorrelates DFT-Calculated Structures and Experimental ProtonChemical Shifts
Mechanism of the Aromatic Hydroxylation of Thiopheneby Acid-Catalyzed Peracid Oxidation.
Synthesis and Characterization ofβ-Trifluoromethyl-meso-tetraphenylporphyrins
Two Novel Cytotoxic Cyclodepsipeptidesfrom a Mycoparasitic Cladobotryum sp.
Complete Control of Regioselectivity in theIntramolecular [2 + 2] Photocycloadditionof 2-Alkenyl-3(2H)-furanones by the Lengthof the Side Chain
Enantioselective Synthesis of Piperidine, Indolizidine, andQuinolizidine Alkaloids from a Phenylglycinol-Derived δ-Lactam
A Practical Route to3‘-Amino-3‘-deoxyadenosine Derivativesand Puromycin Analogues
Asymmetric Synthesis of HighlySubstituted β-Nitro Alcohols andEnantiomerically Enriched4,4,5-Trisubstituted Oxazolidinones
Synthesis of a New Chiral Bisphospholane Ligand for theRh(I)-Catalyzed Enantioselective Hydrogenation of Isomericβ-Acylamido Acrylates
β-Silyl-Substituted Silaadamantyl, Silabicyclo[2.2.2]octyl,Silanorbornyl, and 1-Silacyclohexyl Cations. A Theoretical (DFTand GIAO NMR) Study
Studies on Hydrozirconation of 1-Alkynyl Sulfoxides or Sulfonesand the Application for the Synthesis of Stereodefined VinylSulfoxides or Sulfones
Reverse Turn Induced π-Facial Selectivity duringPolyaniline-Supported Cobalt(II) Salen Catalyzed AerobicEpoxidation of N-Cinnamoyl l-Proline Derived Peptides
Kinetic Isotope Effect Evidence for aConcerted Hydrogen Transfer Mechanismin Transfer Hydrogenations Catalyzed by[p-(Me2CH)C6H4Me]Ru-(NHCHPhCHPhNSO2C6H4-p-CH3)
Stereoselective Synthesis of 1‘-C-BranchedArabinofuranosyl Nucleosides viaAnomeric Radicals Generated by1,2-Acyloxy Migration
Rearrangement of 5-Trimethylsilylthebaine on Treatment withL-Selectride: An Efficient Synthesis of (+)-Bractazonine
Catalysis of the Michael Addition Reaction by Late TransitionMetal Complexes of BINOL-Derived Salens
1H NMR Studies of Maltose, Maltoheptaose, α-, β-, andγ-Cyclodextrins, and Complexes in Aqueous Solutions withHydroxy Protons as Structural Probes
Aromatic Allylation via Diazotization: Variation of the AllylicMoiety and a Short Route to a Benzazepine Derivative
Synthesis and Structure of a Stabilized 10-Membered Cyclic Enediyne.
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