About: Total Synthesis of Microcarpalide

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/joceah/2005/volume_70/issue_10/w
Subject	Note
Title	Total Synthesis of Microcarpalide
has manifestation of work	http://hub.abes.fr/acs/periodical/joceah/2005/volume_70/issue_10/101021jo050193e/m/print http://hub.abes.fr/acs/periodical/joceah/2005/volume_70/issue_10/101021jo050193e/m/web
related by	http://hub.abes.fr/acs/periodical/joceah/2005/volume_70/issue_10/101021jo050193e/authorship/1 http://hub.abes.fr/acs/periodical/joceah/2005/volume_70/issue_10/101021jo050193e/authorship/2
Author	Naidu S. Vasudeva Kumar Pradeep
Abstract	An efficient, convergent approach for the total synthesis ofmicrocarpalide (1) is described. The synthetic strategyfeatures the Sharpless asymmetric dihydroxylation, regioselective epoxide opening with various nucleophiles such asa lithium acetylide and cuprates derived from the vinylstannane and the vinyl iodide for the construction of a C7−C8 trans-double bond and Yamaguchi macrolactonization asthe key steps.
article type	brief-report
is part of this journal	The Journal of Organic Chemistry

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