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Systematic Study of the Synthesis of Macrocyclic Dipeptideβ-Turn Mimics Possessing 8-, 9-, and 10- Membered Rings byRing-Closing Metathesis
Convenient Synthesis of ε-Halo-β-ketoesters andγ,γ‘-Dibromoalkanones by Regio- and Chemoselective Reaction of2-Alkylidenetetrahydrofurans with Boron Trihalides:A “Ring-Closure/Ring-Cleavage” Strategy
Novel Deoxygenation Reaction of Epoxides by Indium
Addition of Cl2C: to (−)-O-MenthylAcrylate under Sonication−Phase-TransferCatalysis. Efficient Synthesis of (+)- and(−)-(2-Chlorocyclopropyl)methanol
Synthesis and Properties of Hexakis(6-octyl-2-azulenyl)benzene asa Multielectron Redox System with Liquid Crystalline Behavior
Enantioselective Synthetic Method forα-Alkylserine via Phase-Transfer CatalyticAlkylation of 2-Phenyl-2-oxazoline-4-carbonylcamphorsultam
Synthesis and Structural Analysis of the Anilides of GlucuronicAcid and Orientation of the Groups on the CarbohydrateScaffolding
Solvent-Free Reaction of Some 1,2-Diaza-1,3-butadienes withPhosphites: Environmentally Friendly Access to NewDiazaphospholes and E-Hydrazonophosphonates
Convenient Synthesis of Substituted Piperidinones fromα,β-Unsaturated Amides: Formal Synthesis of Deplancheine,Tacamonine, and Paroxetine
Regioselective Synthesis of 1,5-Diaryl-1H-imidazoles byPalladium-Catalyzed Direct Arylation of 1-Aryl-1H-imidazoles
Photoreactions of 1-Acetylisatin with Alkynes: Regioselectivity inOxetene Formation and Easy Access to 3-Alkylideneoxindoles andDispiro[oxindole[3,2‘]furan[3‘,3‘ ‘]oxindole]s
Cyclopropylcarbinyl → Homoallyl-TypeRing Opening of Ketyl Radical Anions.Structure/Reactivity Relationships and theContribution of Solvent/CounterionReorganization to the Intrinsic Barrier
A Theoretical Investigation of α-Carbon Kinetic Isotope Effectsand Their Relationship to the Transition-State Structure of SN2Reactions
Oxidative Cyclorelease from Soluble Polymeric Supports
α-N-Acetylmannosamine (ManNAc) Synthesis viaRhodium(II)-Catalyzed Oxidative Cyclization of Glucal3-Carbamates
Functionalized Azabicycloalkane Amino Acids by Nitrone1,3-Dipolar Intramolecular Cycloaddition
Isolation, X-ray Structures, and Electronic Spectra of ReactiveIntermediates in Friedel−Crafts Acylations
Synthesis of Structurally Defined Scaffolds for Bivalent LigandDisplay Based on Glucuronic Acid Anilides. The Degree ofTertiary Amide Isomerism and Folding Depends on theConfiguration of a Glycosyl Azide
A New Interpretation of the Baylis−Hillman Mechanism
Intramolecular Cyclization of δ-Iminoacetylenes: A New Entry toPyrazino[1,2-a]indoles
Microwave-Assisted Synthesis of Isonitriles: A General Simple Methodology.
Preparation of Multisubstituted Allenes from Allylsilanes
Unexpected Formation of Polysubstituted 1-Azabutadienes and1,3-Dioxanes from the Reaction of3-Fluoroalkyl-3-arylaminoacrylic Acid Esters with Formaldehyde
Anthryl-Substituted Heterocycles as Acid-Sensitive FluorescenceProbes
Design of Sulfides with a LockedConformation as Promoters of Catalyticand Asymmetric Sulfonium YlideEpoxidation
Reactivity of MethylMandelate−Ti(IV)-enediolate: OxidativeHomocoupling versus Aldol and DirectMannich-Type Syn-DiastereoselectiveCondensation
Stereoselective Addition of the TitaniumEnolate of N-Acetyl(4S)-Isopropyl-1,3-thiazolidine-2-thione toFive-Membered N-Acyl Iminium Ions
1,2-Thio Group Migration in Rh(II)Carbene Reactions
Synthesis of Optically Pure 1,2-Diaryl- and 1,2-Alkylaryl-1,2-aminoSulfides
Total Synthesis of Microcarpalide
An Evolved Explanation for the Molecular Geometry andElectronic Structure of Diphenyl-Substituted CyclicTrimethylenemethane in the Ground State: A Nearly PlanarConformation with a Considerably Localized Electronic State
Regio- and Stereoselective Route to Tetrasubstituted Olefins bythe Palladium-Catalyzed Three-Component Coupling of ArylIodides, Internal Alkynes, and Arylboronic Acids
Syntheses of 2,5-Disubstituted Dihydrofurans from γ-SubstitutedChiral Allenamides
BODIPY-Based Hydroxyaryl Derivatives as Fluorescent pH Probes
Efficient Unimolecular Deprotonation of Aniline Radical Cations
N-Methylation of Peptides on Selected Positions during theElongation of the Peptide Chain in Solution Phase
Controlled Synthesis of Cis or Trans Isomers of 1,3-DisubstitutedTetrahydroisoquinolines and 2,5-Disubstituted Pyrrolidines
Manganese(III)-Mediated Oxidative Annulation ofMethylenecyclopropanes with 1,3-Dicarbonyl Compounds
Practical and Efficient MultigramPreparation of a Camphor-Derived Diol forthe Enantioselective Lewis Acid CatalyzedAllylboration of Aldehydes
Stereoselective Suzuki−Miyaura Cross-Coupling Reactions ofPotassium Alkenyltrifluoroborates with Alkenyl Bromides
Gas-PhaseKinetics and Activation Parameters for Thermal [1,5] HydrogenShifts Interconverting Monodeuterium-Labeled 1,3-Cycloheptadienes.
Palladium-Catalyzed Coupling of PyrazoleTriflates with Arylboronic Acids
Determining the Absolute Stereochemistry of Secondary/Secondary Diols by 1H NMR: Basis and Applications
Synthesis of (+)-6β−Isovaleryloxylabda-8,13-diene-7α,15-diol, a Metabolite fromTrismusculus reticulatus
meso-Alkyl-Substituted meso-meso Linked Diporphyrins andmeso-Alkyl-Substituted meso-meso, β-β, β-β Triply LinkedDiporphyrins
Microwave-Assisted Multistep Synthesis of Functionalized4-Arylquinolin-2(1H)-ones Using Palladium-CatalyzedCross-Coupling Chemistry
Biocatalytic Racemization of Aliphatic, Arylaliphatic, andAromatic α-Hydroxycarboxylic Acids
Synthetic Approaches and Total Synthesisof Natural Zoapatanol.
A General Strategy for the Synthesis of Vincamajine-RelatedIndole Alkaloids: Stereocontrolled Total Synthesis of(+)-Dehydrovoachalotine, (−)-Vincamajinine, and(−)-11-Methoxy-17-epivincamajine as Well as the RelatedQuebrachidine Diol, Vincamajine Diol, and Vincarinol1
Syntheses of StableN-tert-Alkoxyarylaminyl Mono- andDiradicals by the Reaction of the LithiumSalts of 2,4,6-Trisubstituted Anilines withtert-Alkyl Mono- and Diperoxybenzoates1
Synthesis of 3‘-Deoxy-3‘-difluoromethyl Azanucleosides fromtrans-4-Hydroxy-l-proline
A Controllable Synthesis of Homoallyl Ketones and MultiplySubstituted Cyclopentadienes by Direct Insertion of AroylCyanides to Zirconacyclopentenes
One-Pot Friedel−Crafts/Robinson−GabrielSynthesis of Oxazoles Using OxazoloneTemplates
Are Electrocyclization Reactions of (3Z)-1,3,5-Hexatrienone andNitrogen Derivatives Pseudopericyclic? A DFT Study
Cyclic Nitriles: Diastereoselective Alkylations
An Unprecedented Concerted Pathway inthe Alkaline Hydrolysis of S-ArylThioesters
Stereodivergent Syntheses of Anisomycin Derivatives fromd-Tyrosine
NiCl2-Catalyzed Hydrophosphinylation
Ketone-Imide versus Ketone-Oxime Reductive Cross-CouplingPromoted by Samarium Diiodide: New Mechanistic InsightGained from a Failed Aminocyclopentitol Synthesis
Adducts of Thianthrene- and Phenoxathiin Cation Radical Saltswith Symmetrical Alkynes. Structure and Formation ofCumulenes on Alumina Leading to α-Diketones,α-Hydroxyalkynes, and α-Acetamidoalkynes
Determination of Molecular Structure Using Vibrational CircularDichroism Spectroscopy: The Keto-lactone Product ofBaeyer−Villiger Oxidation of(+)-(1R,5S)-Bicyclo[3.3.1]nonane-2,7-dione
Crucial Role of Elusive Isomeric η-Complexes in Gas-PhaseElectrophilic Aromatic Alkylations
An N-Acyliminium Cyclization Approach to a Total Synthesis of(+)-Cylindricine C
Factors Affecting Stereocontrol duringGlycosidation of2,3-Oxazolidinone-Protected1-Tolylthio-N-acetyl-d-glucosamine
Palladium(II)-Catalyzed Enyne Coupling Reaction Initiated byAcetoxypalladation of Alkynes and Quenched by Protonolysis ofthe Carbon−Palladium Bond
The Effect of Ring Substitution on the O-Neophyl Rearrangementof 1,1-Diarylalkoxyl Radicals. A Product and Time-ResolvedKinetic Study
Formation of Stable Meisenheimer Adduct Ion Pairs in ApolarSolvents: Implications for Stereoselective Reactions
Convenient Route to Both Enantiomers ofa Highly FunctionalizedTrans-Disubstituted Cyclopentene.Synthesis of the Carbocyclic Core of theNucleoside BCA
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