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À propos de : Syntheses of 2,5-Disubstituted Dihydrofurans from γ-SubstitutedChiral Allenamides        

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  • Syntheses of 2,5-Disubstituted Dihydrofurans from γ-SubstitutedChiral Allenamides
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  • Details of a synthesis of dihydrofurans using γ-substituted chiral allenamides are described here.Some transformations of these dihydrofurans are also examined including a highly stereoselectivedihydroxylation and a rare account of a Lewis acid-mediated removal of an N-acyl substituent atthe anomeric carbon of a tetrahydrofuran ring system. These studies provide further support forthe synthetic utility of allenamides.
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