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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/jpcbfk/2006/volume_110/issue_16/w
Subject	Letter
Title	On the Nonequilibrium Thermodynamics of Large Departures from Butler−VolmerBehavior
has manifestation of work	http://hub.abes.fr/acs/periodical/jpcbfk/2006/volume_110/issue_16/101021jp060506p/m/web http://hub.abes.fr/acs/periodical/jpcbfk/2006/volume_110/issue_16/101021jp060506p/m/print
related by	http://hub.abes.fr/acs/periodical/jpcbfk/2006/volume_110/issue_16/101021jp060506p/authorship/1
Author	de Miguel Rodrigo
Abstract	Large deviations from the behavior predicted by the Butler−Volmer equation of electrochemistry are accountedfor using mesoscopic nonequilibrium thermodynamics. The nonequilibrium thermodynamic hypotheses areextended to include velocity space and cope with imperfect reactant transport leading to departures fromButler−Volmer behavior. This results in a modified Butler−Volmer equation in good agreement withexperimental data. The distinct advantages of the method and its applicability to analyze other systems arebriefly discussed.
article type	rapid-communication
is part of this journal	The Journal of Physical Chemistry B

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