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À propos de : 1,6-Bis(ferrocenyl)-1,3,5-hexatriyne: Novel Preparation andStructural Study        

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  • 1,6-Bis(ferrocenyl)-1,3,5-hexatriyne: Novel Preparation andStructural Study
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  • 1,6-Bis(ferrocenyl)-1,3,5-hexatriyne (Fc(C⋮C)3Fc)was prepared from the reaction between 3-(dibromomethylidene)-1,5-bis(ferrocenyl)penta-1,4-diyne and BuLi via analkynyl migration in a vinylidene carbenoid mechanism. Boththe title compound and its precusors were thoroughly characterized, and the electronic couplings between two ferrocenyl unitswere assessed with voltammetric techniques.
  • 1,6-Bis(ferrocenyl)-1,3,5-hexatriyne (FcC6Fc) was prepared from the route involving alkynyl migration in a vinylidene carbenoid.
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