About: Direct Formation of Propargyltin Compounds via C−H Activation

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Attributs	Valeurs
type	work Article
Is Part Of	http://hub.abes.fr/acs/periodical/orgnd7/2008/volume_27/issue_13/w
Subject	Communication
Title	Direct Formation of Propargyltin Compounds via C−H Activation
has manifestation of work	http://hub.abes.fr/acs/periodical/orgnd7/2008/volume_27/issue_13/101021om800132h/m/web http://hub.abes.fr/acs/periodical/orgnd7/2008/volume_27/issue_13/101021om800132h/m/print
related by	http://hub.abes.fr/acs/periodical/orgnd7/2008/volume_27/issue_13/101021om800132h/authorship/2 http://hub.abes.fr/acs/periodical/orgnd7/2008/volume_27/issue_13/101021om800132h/authorship/1 http://hub.abes.fr/acs/periodical/orgnd7/2008/volume_27/issue_13/101021om800132h/authorship/3
Author	Kampf Jeff W. Kavara Ajdin Holl Mark M. Banaszak
Abstract	The mixed reagent SnC(SiMe3)2CH2CH2C(SiMe3)2]/ArI reacts with alkynes to give primary and secondary propargylic C−H activation. Alkynes tested include 1-phenylpropyne, 1-phenylbutyne, 1-trimethylsily1hexyne, and 2-hexyne. Aryl halides tested include iodobenzene and 2,4,6-triisopropyliodobenzene. An X-ray crystal structure is reported for the product of the secondary propargylic activation of 2-hexyne.
is part of this journal	Organometallics

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